电子垃圾中(HCI + HNO3)和(HCI + H2SO4)浸出回收贵重重金属技术

Murugesan Manikkampatti Palanisamy, Akilamudhan Palaniappan, V. Myneni, Padmapriya Veerappan, Minar Mohamed Lebba
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摘要

信息技术和工业化的快速发展是电子设备发展的关键组成部分,它们在人类日常生活中不可避免的作用对电子垃圾的产生有着重要的抑制作用。这种废物具有深远的环境和健康后果。其中一个电子垃圾印刷电路板(PCB)含有大量有价值的重金属,如铜(Cu)、铅(Pb)、锌(Zn)、镍(Ni)等,可以通过各种冶金途径提取。重金属离子的回收和循环利用是防止环境污染的重大挑战。本研究详细讨论了当前电子垃圾的现状、健康影响和处理方法,并介绍了王水(HCI + HNO3和HCI + H2SO4)浸出回收印刷电路板(pcb)中重金属的实验结果。在80℃、0.05 mm的厚度、3小时的接触时间、80rpm的摇动速度、0.5 g ml - 1的PCB样品浓度等不同条件下,提取的重金属离子组成为铜占97.59%、铅占96.59%、锡占94.66%、锌占96.64%。多氯联苯中重金属离子的回收在电子废弃物管理中具有重要的主导作用,且回收率较高。
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Leaching Technology for Precious Heavy Metal Recapture through (HCI + HNO3) and (HCI + H2SO4) from E-Waste
The rapid growth of information technology and industrialization are the key components for the development of electronic equipment, and their inevitable role in human day-to-day life has an important stint in the generation of electronic waste (e-waste). This waste has far-reaching environmental and health consequences. One such e-waste printed circuit board (PCB) contains significant amounts of valuable heavy metals such as copper (Cu), lead (Pb), zinc (Zn), nickel (Ni), and others that can be extracted through various metallurgical routes. Recovery and recycle of heavy metal ions is a major challenge to prevent environmental contamination. The present study discusses the current e-waste scenario, health impacts and treatment methods in detail, and also presents experimental results of recovery of heavy metals from printed circuit boards (PCBs) by leaching using aqua regia (HCI + HNO3 and HCI + H2SO4). Under varying conditions such as specified conditions of 80°C, 0.05 mm of thickness, 3 hrs of contacttime, 80rpm shaking speed, and concentration of PCB sample of 0.5 g ml−1, it results in the composition of extracted heavy metal ions in such a way that 97.59% of copper, 96.59% of lead, 94.66% of tin, and 96.64% of zinc, respectively. The recovery of heavy metal ions from PCBs has an important leading contribution in electronic waste management and the result shows a higher rate.
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