乙烯和二氧化碳制丙烯酸催化材料的制备

Carina Ivonne Canul-Cemé, Ricardo Conejo-Flores, J. García-González, J. Guzmán-Pantoja
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引用次数: 0

摘要

二氧化碳排放及其在大气中的积累所造成的环境问题,迫使科学界采取各种方法减少二氧化碳排放,并寻求其使用的替代办法,其中之一是化学合成;与此同时,各种促进催化剂活化的材料也被开发出来。本文介绍了二氧化碳和乙烯制丙烯酸催化剂的合成。所使用的材料是过渡金属:镍和钴,来自盐NiSO4•(NH4)2SO4•6H2O(硫酸铵和六水镍)和CoCl2•6H2O(六水氯化钴)。在此过程中,镍浸渍在聚合物材料中,并被粘土材料吸收;这两种金属都经历了化学还原过程。为了验证材料的组成,对所有获得的材料进行了扫描电子显微镜/ x射线能量色散光谱分析。这里给出的结果是初步的,因此得到丙烯酸的反应还没有深入研究。提出的材料和收集到的信息是未来研究的一个很好的起点。
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Preparation of catalytic materials for obtaining Acrylic Acid from Ethylene and Carbon Dioxide
The environmental problems caused by carbon dioxide emissions, as well as its accumulation in the atmosphere, have forced the scientific community to implement methods to reduce said emissions, as well as to seek alternatives for their use, one of which is in the chemical synthesis; simultaneously, catalysts with various materials that facilitate their activation have been developed. The following research paper presents the synthesis of catalysts for obtaining acrylic acid from carbon dioxide and ethylene. The materials used are transition metals: nickel and cobalt, from the salts NiSO4•(NH4)2SO4•6H2O (ammonium sulfate and nickel hexahydrate) and CoCl2•6H2O (cobalt chloride hexahydrate). During the procedure, nickel is impregnated in a polymeric material and absorbed in a clayey material; both metals are subjected to a chemical reduction process. To verify the composition of the material, a scanning electron microscopy/X-ray energy dispersive spectrometry analysis was performed for allthe obtained materials. The results presented here are initial in the research, so the reaction to obtain the acrylic acid is not yet studied in depth. The proposed materials and gathered information are a good starting point for future research.
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