Silantek煤、棕榈仁壳、棕榈仁壳焦及其混合物燃烧过程的热重分析

M. A. Jamaluddin, K. Ismail, Z. A. Ghani, M. Ishak, S. S. Idris, M. Abdullah, M. Yunus, S. Tahiruddin, Noor Irma Nazashida Mohd Hakimi
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引用次数: 3

摘要

在热重分析仪(TGA)上对Silantek煤(SL)、棕榈仁壳(PKS)、PKS焦及其混合物进行了初步的热重分析。采用功率为300 w的微波辐照碳化系统,氮气流量为150 mL/min,焙烧30 min制备PKS焦。原料和混合样品的燃烧试验在净化空气气氛条件下进行,加热速率为20°C/min。分别以80:20、60:40、50:50、40:60和20:80的质量比制备SL/ PKS和SL/ PKS共混物。衍生热重(DTG)分析结果表明,原料PKS在燃烧过程中比SL具有更高的反应活性。SL: PKS共混物的热分布与共混物中PKS的添加百分比相关,表明两种样品之间缺乏协同效应。SL和PKS混合燃烧产生单一演化峰,表明了作为替代燃料燃烧的可能性。这些发现可能对发电行业开发未来使用煤/生物质的共烧电厂有用;然而,在大规模实施之前,需要进行大量的开发工作。
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Thermogravimetric analysis of Silantek coal, Palm Kernel Shell, Palm Kernel Shell char and their blends during combustion
Preliminary thermogravimetric studies of Silantek coal (SL), Palm Kernel Shell (PKS), PKS char and their blends have been performed in a Thermogravimetry Analyser(TGA). PKS char were produced using microwave irradiation carbonization system at power of 300 Watt, with nitrogen flow rate of 150 mL/min for 30 minutes. Combustion tests of raw and blends samples were carried out in purified air atmosphere conditions at heating rates of 20 °C/min. The SL/ PKS and SL/ PKS char blends were prepared in the weight ratios of 80:20, 60:40, 50:50, 40:60 and 20:80. Derivative thermogravimetric (DTG) results which represent the decomposition of volatile matters and char showed that raw PKS has higher reactivity than SL during combustion process. The thermal profiles of the SL: PKS blends correlated with the percentage of PKS added in the blends, representing lack of synergic effect between both samples. SL and PKS char blends results in single evolution peak, indicated possibility to be used as alternative fuel for combustion. These findings may be useful for the power generation industry in the development of future co-firing plants using coal/ biomass; however, significant development work is required before large-scale implementation can be done.
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