利用调制单质反应物可重复合成(Bi/sub 2/Te/sub 3/)/sub 5/(TiTe/sub 2/)/sub 4/超晶格

M. Smeller, Fred R. Harris, David C. Johnson
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引用次数: 0

摘要

可靠的合成技术对工业热电应用至关重要。采用调制单质反应物(MER)法制备了7个(Bi/sub 2/Te/sub 3/)/sub 5/(TiTe/sub 2/)/sub 4/超晶格,超晶格周期可重复性在0.6%以内。这些样品的电学性能受缺陷分布和密度的控制。270℃退火后,Seebeck系数由-60 /spl mu/V/K变为-200 /spl mu/V/K。
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Repeatable synthesis of (Bi/sub 2/Te/sub 3/)/sub 5/(TiTe/sub 2/)/sub 4/ superlattices using modulated elemental reactants
Reliable synthesis techniques are essential for industrial thermoelectric applications. The modulated elemental reactant (MER) method was used to make a set of seven (Bi/sub 2/Te/sub 3/)/sub 5/(TiTe/sub 2/)/sub 4/ superlattices, with a superlattice period reproducible to within 0.6%. The electrical properties of these samples were controlled by the distribution and densities of defects. Annealing at 270/spl deg/C changed the Seebeck coefficient from -60 /spl mu/V/K to -200 /spl mu/V/K after 111 hours annealing at 270/spl deg/C.
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