纤维素纳米纤维/玻璃纤维增强复合材料的制备及其弯曲性能评价

Y. Xie, H. Kurita, Risa Honda, K. Katabira, F. Narita
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摘要

玻璃纤维增强塑料(GFRP)构件的制造需要一种具有优异力学性能的连接技术。然而,众所周知,机械连接往往会导致纤维增强塑料的断裂。认为胶粘剂粘接适用于接缝gfrp,有必要开发一种具有优异力学性能的胶粘剂。近年来,人们通过机械和化学方法从植物中制备了纤维素纳米纤维,并报道了纤维素纳米纤维具有优异的力学性能。在这项研究中,我们将环氧树脂与CNFs插入GFRP之间,并研究其弯曲行为,以评估环氧树脂与CNFs作为GFRP的粘合剂的能力。在GFRP中加入CNFs层的环氧树脂后,GFRP的抗弯性能和模量基本相同。GFRP的抗弯强度在添加5%或10% CNFs的环氧树脂后得到显著提高(可达600 MPa),而添加25% CNFs的环氧树脂会降低GFRP的抗弯强度。因此,CNFs环氧树脂作为GFRP的粘结剂是可行的。但要了解CNFs对环氧树脂的强化机理,还需要观察CNFs在环氧树脂中的分散情况。
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Fabrication of Cellulose Nanofiber/Glass Fiber-reinforced Composites and Their Bending Behavior Evaluation
It is required a joint technic with excellent mechanical properties to fabricate glass fiber reinforced plastic (GFRP) components. However, it is well-known that the mechanical jointing often causes the fracture of fiber reinforced plastics. It seems that the adhesive bonding is suitable to joint GFRPs, and it is necessary to develop an adhesive with outstanding mechanical properties. Recently, cellulose nanofibers (CNFs) have been obtained from plants by mechanical and chemical methods and it has been reported that CNFs have remarkable mechanical properties. In this study, we inserted epoxy resin with CNFs between GFRP and investigated its bending behavior, to estimate the capability of epoxy resin with CNFs as an adhesive for GFRPs. The flexural behavior and modulus of GFRP was similar regardless of the inserted part of epoxy resin with CNFs layer in GFRP. The flexural strength of GFRP was drastically increased (up to 600 MPa) by the insert of epoxy resin with CNFs of 5 or 10 wt.%, although that of GFRP was decreased by the insert of epoxy resin with CNFs of 25 wt.%. Therefore, it seems that the epoxy resin with CNFs is available as an adhesive for GFRP. However, it is required the observation of CNFs dispersion in epoxy resin to understand the strengthening mechanism of epoxy resin with CNFs.
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