两种介质纳米结构提高钙钛矿太阳能电池效率的比较分析

Nayem Hasen, Aminur Rahman, Showmik Singha, Tahmid Aziz Chowdhury
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摘要

钙钛矿(CH3NH3PbI3)太阳能电池(PSCs)具有高吸收率、低成本、易于制造和快速提高效率等优点,近年来得到了广泛的应用。近年来,有机金属卤化物钙钛矿作为吸收层的有效性已超过20%。电介质纳米结构被认为是第三代光伏(如psc)的可能选择,因为它具有更低的损耗和更简单的制造工艺。另一方面,介电纳米结构增透涂层最近作为一种减少反射和提高薄膜吸收器功率转换效率(PCE)的方法而出现,而薄膜吸收器以前效率很低。在本研究中,在钙钛矿吸收层上使用了两种不同类型的纳米结构,减少了光反射,增强了太阳能电池的功率吸收、短路电流和效率。此外,还证明了改变纳米结构尺寸对吸收增强的影响。利用时域有限差分(FDTD)和光电耦合模型,所提出的优化纳米结构具有大于90%的功率吸收,最大光电流增强。与传统平面PSCs相比,总光电流增加了17-20%,最大PCE为16.78%,在整个波长范围内增强了37%。
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A Comparative Analysis of Two Dielectric Nanostructures to Enhance Efficiency of Perovskite Solar Cells
Perovskite (CH3NH3PbI3) solar cells (PSCs) have recently been invented due to their desirable characteristics such as high absorption, low cost, ease of fabrication, and rapidly improving efficiencies. In recent years, the effectiveness of organometallic halide perovskite as an absorber layer has already surpassed 20%. Dielectric nanostructures are being considered as a possible option for third generation photovoltaics, such as PSCs, due to lower losses and simpler fabrication. Dielectric nanostructured antireflection coatings, on the other hand, have recently emerged as a method for reducing reflection and improving the power conversion efficiency (PCE) of a thin-film absorber that was previously inefficient. In this research, two different types of nanostructures are used on the perovskite absorber layer that reduced light reflection and enhanced the power absorption, short-circuit current, and efficiency of the solar cells. Furthermore, as demonstrated how changing the nanostructure size has an effect on the absorption enhancement. Utilizing the finite difference time domain (FDTD) and coupled optical-electrical models, the proposed optimum nanostructures exhibit greater than 90% power absorption, with the maximum enhanced photocurrent. Total photocurrent increased by 17-20% compared to conventional planar PSCs, with a maximum PCE of 16.78%, representing 37% enhancement throughout the entire wavelength range.
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