{"title":"掺杂Pr3+离子的Sr9RE(PO4)7 (RE = Sc, Lu)配合磷酸盐的快速5d-4f发光","authors":"E. Trofimova, V. Pustovarov, Q. Shi","doi":"10.1063/1.5134329","DOIUrl":null,"url":null,"abstract":"The paper studies 5d→4f transitions in Sr9RE(PO4)7 (RE = Sc, Lu) doped with Pr3+ under X-ray and ultraviolet (UV) excitation at various temperatures and with different Pr3+ ions content. In objects with Sc, 5d → 4f emission is negligible compared to 4f → 4f emission. When Sc is substituted with Lu, 5d → 4f transition emission yield is immense under excitation in both energy ranges, while emission related to 4f → 4f transitions is weak, especially under UV excitation. X-ray luminescence yield strongly depends on temperature; the effect is stronger for objects with Lu. Luminescence decay kinetics measured for Sr9Sc(PO4)7:Pr3+ have a fast (τ∼15 ns) component. Novel Pr3+-doped phosphors may be used as a promising material for fast efficient converters of ionizing radiation.The paper studies 5d→4f transitions in Sr9RE(PO4)7 (RE = Sc, Lu) doped with Pr3+ under X-ray and ultraviolet (UV) excitation at various temperatures and with different Pr3+ ions content. In objects with Sc, 5d → 4f emission is negligible compared to 4f → 4f emission. When Sc is substituted with Lu, 5d → 4f transition emission yield is immense under excitation in both energy ranges, while emission related to 4f → 4f transitions is weak, especially under UV excitation. X-ray luminescence yield strongly depends on temperature; the effect is stronger for objects with Lu. Luminescence decay kinetics measured for Sr9Sc(PO4)7:Pr3+ have a fast (τ∼15 ns) component. Novel Pr3+-doped phosphors may be used as a promising material for fast efficient converters of ionizing radiation.","PeriodicalId":418936,"journal":{"name":"PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference","volume":"19 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2019-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Fast 5d-4f luminescence in Sr9RE(PO4)7 (RE = Sc, Lu) complex phosphates doped with Pr3+ ions\",\"authors\":\"E. Trofimova, V. Pustovarov, Q. Shi\",\"doi\":\"10.1063/1.5134329\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The paper studies 5d→4f transitions in Sr9RE(PO4)7 (RE = Sc, Lu) doped with Pr3+ under X-ray and ultraviolet (UV) excitation at various temperatures and with different Pr3+ ions content. In objects with Sc, 5d → 4f emission is negligible compared to 4f → 4f emission. When Sc is substituted with Lu, 5d → 4f transition emission yield is immense under excitation in both energy ranges, while emission related to 4f → 4f transitions is weak, especially under UV excitation. X-ray luminescence yield strongly depends on temperature; the effect is stronger for objects with Lu. Luminescence decay kinetics measured for Sr9Sc(PO4)7:Pr3+ have a fast (τ∼15 ns) component. Novel Pr3+-doped phosphors may be used as a promising material for fast efficient converters of ionizing radiation.The paper studies 5d→4f transitions in Sr9RE(PO4)7 (RE = Sc, Lu) doped with Pr3+ under X-ray and ultraviolet (UV) excitation at various temperatures and with different Pr3+ ions content. In objects with Sc, 5d → 4f emission is negligible compared to 4f → 4f emission. When Sc is substituted with Lu, 5d → 4f transition emission yield is immense under excitation in both energy ranges, while emission related to 4f → 4f transitions is weak, especially under UV excitation. X-ray luminescence yield strongly depends on temperature; the effect is stronger for objects with Lu. Luminescence decay kinetics measured for Sr9Sc(PO4)7:Pr3+ have a fast (τ∼15 ns) component. Novel Pr3+-doped phosphors may be used as a promising material for fast efficient converters of ionizing radiation.\",\"PeriodicalId\":418936,\"journal\":{\"name\":\"PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference\",\"volume\":\"19 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-12-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1063/1.5134329\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/1.5134329","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Fast 5d-4f luminescence in Sr9RE(PO4)7 (RE = Sc, Lu) complex phosphates doped with Pr3+ ions
The paper studies 5d→4f transitions in Sr9RE(PO4)7 (RE = Sc, Lu) doped with Pr3+ under X-ray and ultraviolet (UV) excitation at various temperatures and with different Pr3+ ions content. In objects with Sc, 5d → 4f emission is negligible compared to 4f → 4f emission. When Sc is substituted with Lu, 5d → 4f transition emission yield is immense under excitation in both energy ranges, while emission related to 4f → 4f transitions is weak, especially under UV excitation. X-ray luminescence yield strongly depends on temperature; the effect is stronger for objects with Lu. Luminescence decay kinetics measured for Sr9Sc(PO4)7:Pr3+ have a fast (τ∼15 ns) component. Novel Pr3+-doped phosphors may be used as a promising material for fast efficient converters of ionizing radiation.The paper studies 5d→4f transitions in Sr9RE(PO4)7 (RE = Sc, Lu) doped with Pr3+ under X-ray and ultraviolet (UV) excitation at various temperatures and with different Pr3+ ions content. In objects with Sc, 5d → 4f emission is negligible compared to 4f → 4f emission. When Sc is substituted with Lu, 5d → 4f transition emission yield is immense under excitation in both energy ranges, while emission related to 4f → 4f transitions is weak, especially under UV excitation. X-ray luminescence yield strongly depends on temperature; the effect is stronger for objects with Lu. Luminescence decay kinetics measured for Sr9Sc(PO4)7:Pr3+ have a fast (τ∼15 ns) component. Novel Pr3+-doped phosphors may be used as a promising material for fast efficient converters of ionizing radiation.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
