氯化废渣二氧化钛产业化研究进展

Li Wang, Ye Luo, Zhuo Sun
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摘要

2012年5月8日,发展改革委、环境保护部、科技部等七部委正式联合印发了《废物资源化利用科技工程“十二五”规划》,规划代码为(国家科学发展规划[2012]116,以下简称《规划》),目的是促进废物资源化、无害化处理处置,实现固体废物的大规模吸收,引领节能环保等战略性新兴产业的发展。在此背景下,中国固废行业进入了一个快速发展的机遇期。20世纪70年代以来,中国立足国情,大力研究和发展氯化二氧化钛技术。经过40年的技术消化和科技攻关,2002年锦州钛业的氯化工艺达到生产标准,标志着中国氯化二氧化钛的工业化生产真正实现。随后,云南新力、河南百利联、河南漯河兴茂钛业等国内企业相继上线,行业转型升级如火如荼。但是,氯化工艺对环境造成的污染必须引起人们的高度重视。有研究认为,与硫酸法相比,氯化渣处理难度较大。传统上,通过填埋或运输到人口稀少的地区或倒入海洋,它对环境的危害更大。社会责任感的极度缺乏是一种非常不负责任的表现。因此,要抓住中国固废产业快速发展的机遇,依托钛白粉产业转型,迫切需要研究氯化工艺废渣的产业化,走循环经济和可持续发展之路是摆在行业面前的必由之路。
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Review on industrialization of titanium dioxide residue from chlorination process
On May 8, 2012, seven ministries, including the Development and Reform Commission, the Ministry of Environmental Protection and the Ministry of Science and Technology, formally jointly issued the "Twelfth Five-Year Plan" for Science and Technology Engineering of Waste Resource Utilization, The program code number (National Science Development Plan [2012] 116, hereinafter referred to as "Planning"), the purpose is to promote the recycling, harmless treatment and disposal of waste, and realize the large-scale absorption of solid waste, so as to lead the development of strategic emerging industries such as energy conservation and environmental protection. In this context, China's solid waste industry has entered a period of rapid development opportunities. Since the 1970s, based on the national conditions, China has vigorously studied and developed the technology of chlorinated titanium dioxide. After 40 years of technological digestion and scientific and technological research, In 2002, the chlorination process of Jinzhou Titanium Industry reached the production standard, which indicated that the industrialized production of chlorinated titanium dioxide in China had really been realized. Subsequently, domestic enterprises such as Xinli in Yunnan, Baili Lian in Henan and Xingmao Titanium Industry in Luohe, Henan, were successively launched, and the transformation and upgrade of the industry were in full swing. However, the environmental pollution caused by chlorination process must be paid more attention. Some studies believe that compared with sulphuric acid process, chlorinated slag treatment is more difficult. Traditionally, it is more harmful to the environment by landfilling or transporting it to sparsely populated areas or pouring it into the sea. The extreme lack of social responsibility is a very irresponsible manifestation. Therefore, to grasp the opportunity of rapid development of solid waste industry in China, relying on the transformation of titanium dioxide industry, it is urgent to study the industrialization of chlorination process waste residue, and to take the road of circular economy and sustainable development is the only way in front of the industry.
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