废旧家电分选再生PP的除污方法及加速热氧化降解材料的鉴定

Y. Matsuo
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摘要

材料回收是同时减少环境影响和成本的有效途径。三菱电机公司实现了“从家电到家电的闭环回收”,即从废弃家电中含有的残余塑料混合物中收集聚丙烯(PP)、聚苯乙烯(PS)和丙烯腈-丁二烯-苯乙烯(ABS),并进行分类回收。在本研究中,将深色再生PP和浅色再生PP用颜色分选机从混合色再生PP中分离出来,再利用塑料抛光机对再生PP进行抛光,去除表面污染。随着表面抛光次数的增加,再生PP的热寿命变长,因此热寿命与污染量有明显的相关性。从再生PP中残铜量与热寿命的关系来看,要在不添加金属失活剂的情况下获得与原生PP相当的耐热性,必须将浅色再生PP中残铜量设定在3ppm以下。
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Study on a Method of Contamination Removal for Recycled PP Sorted from Discarded Household Appliances and the Identification of Materials that Accelerated Thermal Oxidation Degradation
Material recycling is a meaningful way to reduce environmental impacts and costs simultaneously. Mitsubishi Electric Corporation has realized “closed-loop recycling from household appliances to household appliances” in which polypropylene (PP), polystyrene (PS) and acrylonitrile-butadiene-styrene (ABS) are collected from a mixture of residual plastics contained in discarded household appliances and sorted for recycling. In this research, the dark-colored recycled PP and the light-colored recycled PP were separated from the mixed-colored recycled PP using a color sorter, and the recycled PP was polished using a plastic polisher to remove surface contamination. As the number of surface polishings of the recycled PP increased, the heat life became longer, so a clear correlation was seen between the heat life and the amount of contamination. From the relationship between the amount of residual copper in the recycled PP and the heat life, it is necessary to set the amount of residual copper in light-colored recycled PP to less than 3 ppm in order to obtain a heat resistance comparable to that of virgin PP without adding a metal deactivator.
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