CeO2-TiO2纳米复合材料协同作用增强对硝基苯酚和酚红的光催化降解

Pawan S. Rana, P. Solanki, T. Dhiman, A. Ahlawat
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引用次数: 3

摘要

有机化合物是环境中最严重的污染物之一。因此,通过光催化等修复过程从环境中去除这些化合物是很重要的。研究了紫外光催化氧化铈-氧化钛纳米复合材料(ceo2 - tio2 - nc)降解对硝基苯酚(NP)和酚红(PR)的性能。采用共沉淀法合成了CeO2-TiO2nc。x射线衍射(XRD)分析证实了材料的相纯度。紫外-可见吸收研究显示在250-310 nm区域有一个宽峰。在无光、可见光(λ > 400 nm)和紫外光(λ < 400 nm)三种照射条件下进行光催化研究。对NP和PR的最大降解率分别为97.3%和99.8%,反应速率常数k分别为0.42和0.54。这是第一个利用TiO2和CeO2的协同效应来降解NP和PR的研究。在80分钟内,这两种化合物的降解率都超过97%;结果表明CeO2-TiO2nc具有较高的光催化活性。因此,CeO2-TiO2nc可以作为一种经济高效的吸附剂,具有很高的降解有害有机化合物的能力。
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Enhanced Photocatalytic Degradation of p-Nitrophenol and Phenol Red Through Synergistic Effects of a CeO2-TiO2 Nanocomposite
Organic compounds are one of the most severe pollutants occurring in the environment. Hence, it is important to remove these compounds from the environment through remediation processes such as photocatalysis. The present study investigated the photocatalytic degradation of p-nitrophenol (NP) and phenol red (PR) using a cerium oxide-titanium oxide nanocomposite (CeO2-TiO2nc) under UV light. CeO2-TiO2nc was synthesized using the co-precipitation method. An X-ray diffraction (XRD) analysis confirmed the phase purity of the material. A UV-Vis absorption study revealed a broad peak in the 250–310 nm region. The photocatalytic study was performed under three irradiation conditions: no light, visible light (λ > 400 nm), and UV light (λ < 400 nm). The maximum degradation percentage for NP and PR was 97.3% and 99.8%, respectively, with the reaction rate constant (k) of 0.42 and 0.54, respectively. This is the first study to utilize the synergistic effects of TiO2 and CeO2 for degrading NP and PR. Over 97% degradation was achieved for both the compounds in 80 min; this result shows the high photocatalytic activity of CeO2-TiO2nc. Thus, CeO2-TiO2nc can be used as a cost-effective adsorbent with a high capacity to degrade harmful organic compounds.
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