高效率、低成本砷化镓太阳能电池的最新进展

J. Fan, C. Bozler, R. Gale, R. McClelland, R. L. Chapman, G. Turner, H. J. Zeiger
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摘要

通过使用n+/p/p+结构,我们已经成功地在单晶GaAs和Ge衬底上制造了GaAs太阳能电池,在AM1下的转换效率为21%。目前有三种方法可以降低这种电池的成本:在低成本的衬底上制备大颗粒的锗片,在廉价的硅片上制备异质外延锗薄膜,以及在可重复使用的砷化镓衬底上制备薄的单晶砷化镓层。在这三个领域都取得了重要进展。用扫描Nd:YAG激光加热非晶态Ge薄膜,在熔融二氧化硅衬底上获得了2µm × 100µm的微晶。通过瞬态加热在Si衬底上获得了异质外延锗薄膜,并在这种薄膜上生长了外延GaAs层。通过一种名为CLEFT的新工艺,可以从可重复使用的GaAs衬底上分离出薄至5 μ m的单晶GaAs层。制备了一种厚度仅为8 μ m的15% (AMI) GaAs太阳能电池,并将其粘合在玻璃衬底上。随着这些发展,低成本、高效率的砷化镓电池很可能成为现实。
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Recent advances in high efficiency, low-cost GaAs solar cells
By using an n+/p/p+structure, we have previously succeeded in fabricating GaAs solar cells on single-crystal GaAs and Ge substrates, with conversion efficiency of 21% at AM1. Three approaches are being used to lower the cost of such cells, preparation of large-grained Ge sheets on low-cost substrates, preparation of heteroepitaxial Ge films on inexpensive Si sheets, and preparation of thin single-crystal GaAs layers on reusable GaAs substrates. Important advances have been achieved in all three areas. Crystallites 2 µm × 100 µm have been obtained on fused silica substrates by heating amorphous Ge films with a scanned Nd:YAG laser. Heteroepitaxial Ge films have also been obtained on Si substrates by transient heating, and epitaxial GaAs layers have been grown on such films. Single-crystal GaAs layers as thin as 5 µm have been separated from reusable GaAs substrates by a new process named CLEFT. A 15% (AMI) GaAs solar cell, only 8 µm thick and bonded to a glass substrate, has been fabricated. With these developments, low-cost high-efficiency, GaAs cells may well become a reality.
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