ErP5O14晶体的非共振上转换能量转移

Chen Xiao-bo, Chen Xiao-bo, Zhang Guang-Yin, Li Mei-Xian, Li Mei-Xian, L. Kun, Feng Yan, Bi Shi-zhang, Hao Zhao, Song Feng, Song Zeng-Fu, Meng Guang-zheng, Sun Yin-guan, Yang Zhan-Ru, Nie Yu-xin
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引用次数: 3

摘要

本文报道了红色DCM染料激光诱导ErP5O14晶体在紫外至蓝绿色波段的上转换发光现象。确定了每个上转换荧光的上转换通道。当激光波长接近650 nm时,稀土离子间的上转换机制主要为非共振上转换能量转移。非常有趣的是,非共振上转换能量传递是通过稀土离子簇的一种耦合状态直接实现的,离子不与晶格交换声子能量。
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Non-resonant upconversion energy transfer of crystal ErP5O14
This paper reports the upconversion luminescence phenomenon of crystal ErP5O14 in ultraviolet to blue-green wave range induced by red DCM dye laser. The upconversion passage of each upconversion fluorescence is confirmed. It is found that the upconversion mechanism is mainly non-resonant upconversion energy transfers between rare earth ions when laser wavelength is near 650 nm. It is very interesting that the non-resonant upconversion energy transfer is achieved directly through a kind of coupling state of rare earth ion cluster and the ions do not exchange their phonon energy with crystal lattice.
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