二氨基十二烷基磷酸插层Zn/Al高密度脂蛋白的合成及其对镉的吸附性能

Messaadi Mahassene
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引用次数: 0

摘要

本文采用化学共沉淀法合成了Zn/Al双层氢氧化物(ZnAl LDH),并与二氨基十二烷基膦酸(DDPA)直接反应接枝,并用粉末x射线衍射、红外光谱、BET和元素分析对所得固体(ZnAl-DDPA LDH)进行了表征。因此,本研究旨在研究ZnAl-DDPA LDHand对Cd2+的去除效率,考察了吸附浓度、pH、吸附剂剂量、盐和温度等对Cd2+的影响。用Langmuir方程和Freundlich方程对吸附数据进行了分析和拟合。采用拟一级和拟二级动力学模型对吸附动力学进行了分析。
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THE INTERCALATION OF Zn/Al HDL BY THE DIAMINO DODECYL PHOPHONIC ACID: SYNTHESIS AND PROPERTIES OF ADSORPTION OF CADMIUM
A B S T R A C T In this paper, Zn/Al double layered hydroxides (ZnAl LDH) were synthesized by chemical co-precipitation method and grafted with Diamino Dodecyl Phosphonic Acid (DDPA) by direct reaction and the obtained solids (ZnAl-DDPA LDH) were characterized by powder X-ray diffraction, infrared spectroscopy, BET and elemental analysis. So, the present research was aimed to study the removal efficiency of Cd2+ by ZnAl-DDPA LDHand investigated all the parameters of adsorption such as the effect of concentration of Cd2+, effect of pH, adsorbent dose, the effect of salt and temperature. The sorption data were analyzed and fitted to linearized equations of the Langmuir and Freundlich. The kinetics of sorption was analyzed by use of pseudo-first-order and pseudosecond order kinetic models.
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