蓖麻木材热流变学研究及其制浆潜力

Bolade M. Ogunleye, J. Fabiyi, J. Fuwape
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引用次数: 0

摘要

研究了蓖麻木材的热稳定性和流变特性。在氮气气氛中,从20℃加热到600℃,加热速率为10℃/min,热重分析表明,所有聚合物的分解起始温度和最终温度没有变化。通过动态力学分析,研究了在130 ~ 0℃温度范围内,以3℃/min、0.1 ~ 10 Hz多频率下的热行为。n -甲基-2-pyrolidone饱和样品在相同溶剂下浸没时进行测试。热重分析过程中聚合物的分解模式在木材的径向位置相似。在0.1 Hz下,R. heudelotii的玻璃化转变温度(Tg)为45±1℃。内部木材和外部木材的Tg不同。Tg结果表明,在化学-热-机械制浆过程中,n -甲基-2- pyroli酮饱和的红毛茸需要较低的能量消耗。
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Thermal and Rheological Studies of Ricinodendron Heudelotii Wood for Its Pulp Production Potential
Thermal stability and rheological behaviors of Ricinodendron heudelotii wood were investigated. Thermogravimetric analysis conducted at a heating rate of 10 o C/min from 20 to 600 o C in a nitrogen atmosphere indicated that there was no variation in the decomposition of the onset and final temperature for all the polymers. The thermal behaviours were investigated at a temperature range from 130 to 0 o C at 3 o C/min, multi-frequencies of 0.1-10 Hz using dynamic mechanical analysis. N-methyl-2-pyrolidone saturated specimens were tested while submerged under the same solvent. Polymers decomposition pattern during thermogravimetric analysis are similar in the radial position of the wood. The glass transition temperature (Tg) of R. heudelotii is 45±1 o C at 0.1 Hz. The Tg differs from the innerwood to outerwood. The Tg showed that N-methyl-2-pyrolidone saturated R. heudelotii would require low energy consumption during chemi-thermomechanical pulping.
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