加压阳极支撑固体氧化物燃料电池的性能研究

N. Royer, Ryan T. Hamilton, J. Collins, John W. Drazin, D. McLarty
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摘要

市场上可买到的阳极支撑电池(ASC)的有效面积为81平方厘米,在750℃、高达9 bar的压力下,使用定制的加压试验台进行了测试。电池的开路电压(OCV)测量表明,由于电池破裂,存在电池间泄漏。使用50/50的N2/H2 (1.2 SLPM)和瓶装空气(1.5 SLPM)在1、3和9 bar下测量电压特性曲线。在0.70 V时,由于从大气压增压到9 bar,测量到的电流密度从0.37 A·cm−2增加到0.43 A·cm−2。随后的测量是在1.5 SLPM的100%干氢气和1.5 SLPM的100%氧气下进行的。在这些条件下,在9 bar电流密度增加到0.5 A·cm−2。OCV和峰值功率密度的增加比理论建议的要多,这表明平衡的阳极和阴极流速降低了电池上的压差,从而减少了泄漏。这些初步测量结果验证了在加压条件下提高作业性能的巨大潜力。
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Performance of Pressurized Anode Supported Solid Oxide Fuel Cell
A commercially available Anode Supported Cell (ASC) with an active area of 81 cm2 was characterized at pressures up to 9 bar at 750 °C using a custom-built pressurized test stand. Open Circuit Voltage (OCV) measurements of the cell indicated the existence of an intercell leak due to a cracked cell. Voltage characteristic curves were measured at 1, 3, and 9 bar using 50/50 N2/H2 (1.2 SLPM) and bottled air (1.5 SLPM). Measured current density at 0.70 V increased from 0.37 A·cm−2 to 0.43 A·cm−2 as a result of pressurization from atmospheric to 9 bar. Subsequent measurements were taken while flowing 100% dry hydrogen at 1.5 SLPM and 100% oxygen at 1.5 SLPM. Under these conditions at 9 bar the current density increased to 0.5 A·cm−2. The OCV and peak power density increased more than suggested by theory, suggesting that the balanced anode and cathode flow rates reduced the pressure differential across the cell resulting in less leakage. These preliminary measurements validate the significant potential for improved operational performance under pressurized conditions.
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