地下水重金属地质累积指数研究——以尼日利亚卡诺大都市Bompai和Sharada工业区为例

Fatima Yuguda Hassan, Tasi’u Yalwa Rilwanu, B. Usman, Ibrahim Rilwanu Yalwa
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摘要

在Sharada和Bompai工业区,土壤中重金属的浓度水平对地下水质量是有害的。在两个地区共选取了40个采样点。采用电感耦合等离子体原子发射光谱法(ICP-OES)对消解样品进行As、Cd、Cr、Cu、Co、Ni和Pb的分析。利用地理信息系统(GIS)对污染源和影响污染水平因素的时空变化进行建模和表征。利用地质积累指数对水体污染和重金属积累带来的潜在风险进行了评价。结果表明:Bompai周边地区镉和砷最易受污染,平均值分别为0.2 ~ 0.4/mg/l和1.3 ~ 1.6 mg/l;地质富集指数制图显示,砷、镉和铜的富集指数较高,分别为(0.99 ~ 1.48)、(0.01 ~ 0.22)和(0.27 ~ 0.33);湿季Sharada地区的钴污染程度中等,为(-0.39 ~ 0.12);GIS建模和制图结果表明,两区地下水均存在重金属,但Cd浓度较高。研究区西南地区重金属污染最为严重,饮用前需对地下水进行处理,避免重金属危害。
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GEO-Accumulation Index for Heavy Metals in Groundwater: a Study of Bompai and Sharada Industrial Estates, Kano Metropolis, Nigeria
The level of concentration of heavy metal in soil is detrimental to groundwater quality in Sharada and Bompai industrial areas. A total of 40 sampling points were selected from both two areas. The digested samples were analysed for As, Cd, Cr, Cu, Co, Ni and Pb using Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-OES) machine. Geographic Information Systems (GIS) was used to model and present the spatiotemporal changes of the pollution sources and factors affecting the levels of pollution. Pollution in water and potential risks introduced by heavy metal accumulation were assessed using Geo-accumulation index. Results indicated that Cadmium and Arsenic are the most vulnerable around Bompai with mean of 0.2-0.4/mg/l and 1.3-1.6 mg/l respectively, Geo-accumulation index mapping showed that Arsenic, Cadmium and Copper to have high accumulation index ranging from strong to very strong (0.99-1.48), (0.01-0.22) and (0.27-0.33) respectively, Cobalt to have moderate contamination in Sharada (wet season) with (-0.39-0.12) while lead and Chromium has the least contamination index (uncontaminated). GIS modelling and mapping indicated that all the heavy metals were found in the groundwater of the two areas but among them Cd is more concentrated. South-western part of the study area confronts the most serious heavy metal pollution, hence the need for groundwater treatment before drinking to avoid dangers associated with heavy metals.
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