甲醇合成催化剂废料作为新型可持续无水泥混凝土的主要成分

V. Mymrin, Reinaldo H. G. Alarcon, Marília A. Guidolin, K. Alekseev, Rogerio J. Hultmann, Walderson Klitzke, K. Q. Carvalho, F. H. Passig, C. Haminiuk, R. E. Catai
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引用次数: 0

摘要

以甲醇合成催化剂(MSC)废料为主要成分(占70%),与铝土矿加工废料(RM)和废铸造砂(FS)复合制备可持续陶瓷。通过XRD、SEM/EDS/mapping、AAS和LAMMA等多种方法对加热过程中初始组分的化学相互作用进行了研究,结果表明,在加热过程中形成了非晶态的玻璃状新结构,它们填充了孔隙,并压实了陶瓷的结构。在这种情况下,所有重金属和最初工业废物的其他有害元素发生强烈的化学和机械结合,并在酸性环境中转移到不溶性物质。在1050℃烧制后,MSC含量最高的材料轴向电阻值最高,为25.98 MPa。
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Methanol Synthesis Catalyst Waste as the Principal Component of New Sustainable Cementless Concrete
Methanol synthesis catalyst (MSC) waste was applied as the principal component (till 70 wt.%) of sustainable ceramics in composites with bauxite processing waste (RM), and waste foundry sand (FS). The results of the initial components' chemical interaction studies by a complex of methods (XRD, SEM/EDS/mapping, AAS and LAMMA) during heating demonstrated the synthesis of amorphous glasslike new formation, their filling of pores and compaction of the ceramic’s structure. In this case, a strong chemical and mechanical binding of all heavy metals and other hazardous elements of the initial industrial waste occurs with their transfer to an insoluble in an acidic environment. The materials with the highest MSC contents have the highest axial resistance values ill 25.98 MPa after firing at 1050°C.
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