用表面弛豫测量铁-3%硅的表面能

B. Mills, H. Jones, G. Leak
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引用次数: 6

摘要

摘要测定了铁-3%硅合金的表面能为1940±600 erg。在1075-1325°C范围内,通过测量真空退火过程中单晶在(110)取向附近的多重划痕的衰减动力学。在合金中主要通过体积扩散进行传质。单次划痕的表面能值比多次划痕的表面能值高约20%,这可能是因为单次划痕分析的不足。在最高温度(1300°C)下,光滑的划痕轮廓包含(110)平面,并且最接近(110)方向的晶体形成切面。注意到,在1200℃退火时,单晶在(100)取向附近形成了延伸的条纹,其方向是表面轻微倾斜会暴露(100)平面。这些观测结果表明,在普遍的退火条件下,γ-图在(100)处比在(110)处有更深的尖点。
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The Surface Energy of Iron-3% Silicon by Surface-Relaxation Measurements
AbstractThe surface energy of iron-3% silicon alloy has been determined as 1940 ± 600 erg. cm−2 for the range 1075–1325° C by measuring the decay kinetics of multiple scratches on single crystals near (110) orientation during vacuum annealing. Mass transport occurred mainly by volume diffusion in the alloy. Surface-energy values from single scratches were higher by ∼ 20% than those from multiple scratches, probably because of inadequacies in the single-scratch analysis. Facets formed where the smoothed scratch profile contained the (110) plane at the highest temperature (1300° C) only and for the crystal nearest to (110) orientation. It was noted that extended striations formed on a single crystal near (100) orientation on annealing at 1200° C, in the direction for which a small surface tilt would expose the (100) plane. These observations suggest that the γ-plot has a deeper cusp at (100) than at (110) under the annealing conditions prevailing.
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