金属薄膜柔性热电器件的制备与评价

N. Sato, Masatoshi Takeda
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引用次数: 14

摘要

本工作的目的是制造和评估柔性热电(TE)器件。由于其灵活性,预计TE器件的应用领域将会扩大。该装置由放置在2片聚酰亚胺片之间的p型和n型薄膜组成,它可以通过装置外表面之间施加的温差(/spl Delta/T/sub - out/)来发电。/spl Delta/T/sub - out/转化为面内温差(/spl Delta/T/sub - in/),可用于p-n偶的热电发电。当/spl Delta/T/sub - out/为57.8 K时,测得/spl Delta/T/sub - in/为16.7 K,与有限元法计算值吻合较好。计算表明,使用具有高功率因数的TE材料是有效的,而低导热系数对该器件的性能将不那么重要。因此,柔性TE器件选择Chromel为p型,constantan为n型。采用射频溅射法制备了由9对薄膜组成的器件。该器件在/spl下可产生144nw的最大输出,测量值Delta/T/sub - out/ = 28.6 K。根据计算,预测了114 nW at /spl的最大值Delta/T/sub - out/ = 28.6 K,与实测值吻合较好。
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Fabrication and evaluation of a flexible thermoelectric device using metal thin films
The purpose of this work is to fabricate and evaluate a flexible thermoelectric (TE) device. Because of its flexibility, it is expected that application field of the TE device will be enlarged. The device consists of p and n-type thin films placed between 2 polyimide sheets, and it can generate electricity from temperature difference (/spl Delta/T/sub out/) applied between the outer surfaces of the device. The /spl Delta/T/sub out/ is transformed into in-plane temperature difference (/spl Delta/T/sub in/), which can be utilized for thermoelectric power generation by the p-n couple. The /spl Delta/T/sub in/ was measured as 16.7 K when /spl Delta/T/sub out/ was 57.8 K, being in good agreement with calculated value by Finite Element Method. Calculations revealed that the use of TE material with high power factor is effective, and low thermal conductivity will be not so important for this device performance. Chromel as p-type and constantan as n-type was, therefore, selected for the flexible TE device. The device composed of 9 pairs of the films was fabricated by RF-sputtering-method. The device could generate maximum output of 144 nW at /spl Delta/T/sub out/ = 28.6 K in measurement. According to the calculation, maximum out of 114 nW at /spl Delta/T/sub out/ = 28.6 K was predicted, being in good agreement with measured value.
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