高纤维素-木质素农业废弃物在生物反应器中的生物降解

Yonca Kiliç, Roda Gokce Yilmaz Cincin, O. N. Ağdağ
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摘要

生物反应器填埋是一种固体废物处理方法,可快速降解固体废物并获取甲烷。进行渗滤液循环的生物反应器一般采用厌氧操作。高木质素和纤维素含量废物的生物降解是非常困难的。特别是在厌氧条件下(此外,如果缺乏水分),这些废物几乎永远不会分解。本研究研究了半好氧生物反应器对难生物降解且木质素纤维素含量高的废向日葵秸秆的降解和甲烷气体的产生。将向日葵秸秆按不同比例加载到生物反应器中,并与城市生活垃圾(OFSWM)有机组分混合。生物反应器在不同的操作条件下运行。测定了载入生物反应器的废弃物中纤维素、半纤维素、木质素及初始和终态有机物的含量。对渗滤液中的pH、COD、BOD5、TKN、NH4-N等参数进行了分析,并对总气量和甲烷气进行了测定。最初,所有的生物反应器都是厌氧操作的。在向日葵秸秆的分解过程中,厌氧生物反应器的有机物去除率为43%,半好氧/厌氧生物反应器的有机物去除率为60%。然后,其他农业废弃物在半好氧/厌氧操作条件下进行分解。研究结果表明,半好氧预处理加速了木质素和纤维素含量高的农业废弃物的分解,降低了渗滤液的COD值,增加了甲烷的量。
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Biodegradation of High Cellulose-Lignin Content Agricultural Wastes in Bioreactors
The bioreactor landfill is a solid waste disposal method that provides rapid solid waste degradation and acquisition of methane. Bioreactors in which leachate circulation is carried out are generally operated anaerobically. The biodegradation of wastes with high lignin and cellulose content is very difficult. Especially under anaerobic conditions (moreover, if there is a lack of moisture), such wastes almost never decompose. In this study, the degradation of the waste sunflower stalks that are difficult to biodegrade and have a high lignin-cellulose content and the production of methane gas in semi-aerobic bioreactors have been investigated. Sunflower stalk, were loaded into the bioreactors in different proportions and mixed with the organic fraction of municipal solid waste (OFSWM). The bioreactors were operated under different operating conditions. The contents of cellulose, hemicellulose, lignin, and initial and final organic matter in the wastes loaded into the bioreactors were examined. Parameters such as pH, COD, BOD5, TKN, NH4-N in leachate were analyzed, and the amounts of total and methane gas were measured. Initially, all bioreactors were operated anaerobically. In the decomposition of the sunflower stalk, while 43% of the organic matter removal was achieved in the anaerobic bioreactor, 60% of the organic matter removal was realised in the semi-aerobic/anaerobic bioreactor. Thereupon, other agricultural wastes were subjected to decomposition under semi-aerobic/anaerobic operating conditions. As a result of the study, it can be said that semi-aerobic pretreatment accelerates the breakdown of agricultural wastes with high lignin and cellulose content, decreases the COD values of leachate, and increases the amount of methane.
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