关于热力学耐热系统中热能和部件质量的扩散传递

V. Ivanov, V. Skachkov, T. Nesterenko, А. Kharchenko
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摘要

不可挽回的能量和物质质量传递过程热力学是一个特殊的科学方向,它研究热力学第二原理方程作为热力学系统与环境合作过程中基本体积内能量和物质质量平衡的起始数学模型。根据不可挽回过程的热力学位置,热量和物质质量传递过程的动力是矢量的,根据居里原理,它们的完全可能组合,预先决定热能流的力可以导致质量流和前后。研究了与环境相互交换热能和质量的封闭热力学耐热系统。由于系统中传递过程中缺乏对流成分,所述过程受到限制。在扩散传递过程中,系统的体积不会改变,由于系统焓的变化,由于热能和质量浓度的变化,它可能被忽略。对存在和不存在交叉效应时热力学耐热系统中各组分的热能和质量的扩散传递进行了数学设计。
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ABOUT DIFFUSIVE TRANSFER OF THERMAL ENERGY AND MASS OF COMPONENTS IN THERMODYNAMICS HEAT-RESISTANT SYSTEMS
Thermodynamics of irretrievable processes of transfer of energy and mass of matter is the special scientific direction, which examines equalition of the second principle of thermodynamics as starting mathematical model for balance of energy and mass of matter in the elementary volume of the thermodynamics system during it cooperating with an environment. In accordance with positions of thermodynamics of irretrievable processes motive forces of processes of transfer of warmth and mass of matter are by vectors and according to principle Curie their fully possible combination, id est force which predetermines stream of thermal energy can to entail a mass stream and back to front. The closed thermodynamics heat-resistant system which interchanges thermal energy and mass of components with an environment is examined. The noted process is limited by absence of convective constituent of process of transfer in the system. The volume of the system does not change during a diffusive transfer and by treason of enthalpy in the system, as by the result of treason of thermal energy and concentration of mass, it is possible to neglect. The mathematical design of diffusive transfer of thermal energy and mass of components in the thermodynamics heatresistant system at presence of and to absence of cross effects is executed.
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