马蹄莲增强聚酯复合材料的热物理性能研究

R. Orhan, E. Aydoğmuş
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引用次数: 5

摘要

在本研究中,利用生物质废弃物制备了既环保又经济的不饱和聚酯复合材料。使用可再生生物质废弃物作为填料在不饱和聚酯减少碳足迹的复合材料所获得的。根据聚酯复合材料的预期用途,可以实现低密度和柔性结构。未添加生物质的纯聚酯聚合物的密度约为1206 kg/ m3,而添加5%填料的复合材料的密度降至1167 kg/ m3。生物质废弃物(Asphodelus aestivus L.)降低了聚酯复合材料的邵氏硬度,使其成为更灵活、更易于加工的材料。研究发现,与纯聚酯复合材料相比,生物质增强聚酯复合材料的导热系数略有提高。此外,还确定了随着聚酯复合材料中生物质用量的增加,活化能降低。用傅里叶变换红外光谱(FTIR)测定了聚酯聚合物的特定键结构。生物质废料不会与聚酯形成化学键,它只是用作填充物。此外,还利用扫描电子显微镜(SEM)研究了聚酯复合材料的表面形貌。使用3 wt.%的aestivus L.生物量作为填料不会在复合材料表面产生负孔隙结构。
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Investigation of some thermophysical properties of Asphodelus aestivus reinforced polyester composite
In this research, both environmentally friendly and economical composites have been produced by using biomass wastes in unsaturated polyester. The use of renewable biomass wastes as a filler in unsaturated polyester is reduced the carbon footprint of the composite obtained. A low-density and flexible structure could be achieved according to the intended use of polyester composites. While the density of the pure polyester polymer not reinforced with biomass is around 1206 kg/m 3 , the density of the 5 wt.% filler added composite decreases to 1167 kg/m 3 . Biomass waste ( Asphodelus aestivus L. ) reduces Shore D hardness of the polyester composite and turns it into a more flexible and easy-to-process material. It has been observed that the thermal conductivity coefficient of the biomass reinforced polyester composite shows a slight increase compared to the pure polyester composite. Besides, it has been determined that as the amount of biomass in the polyester composite increases, the activation energy decreases. The specific bond structure in the polyester polymer has been determined by Fourier transform infrared (FTIR) spectroscopy. Biomass waste is not making a chemical bond with polyester, it is only used as a filler. Also, the surface morphology of the polyester composite has been investigated with the help of scanning electron microscopy (SEM). The use of 3 wt.% Asphodelus aestivus L. biomass as a filler does not create a negative pore structure on the composite surface.
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