利用技术冶金原料生产具有钙长石相的陶瓷材料

M. Semenovykh, N. Skripnikova, O. Volokitin, V. Shekhovtsov
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摘要

研究的主题是获得用于建筑目的的陶瓷材料与钙长石相。以粘土和高炉煤气清洗污泥为原料。研究了陶瓷产品生产中所用原料的化学成分。气体净化污泥组成中的含钙和含铁化合物有助于降低固溶体和钙长石相形成的温度。已经确定,在陶瓷混合物的组成中添加高达80wt .%的污泥会增加钙长石相形成的可能性。对所得陶瓷样品的物理力学参数进行了研究。已经确定,在装料组成中,气体清洗污泥的量为10 - 40 wt.%,可以获得抗压强度比对照样品高18%的产品。物理力学性能的改善与钙长石相数量的增加有关,x射线相分析数据证实了这一点。
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THE USE OF TECHNOGENIC METALLURGICAL RAW MATERIALS FOR THE PRODUCTION OF CERAMIC MATERIALS WITH AN ANORTHITE PHASE
Studies have been carried out on the topic of obtaining ceramic materials for construction purposes with an anorthite phase. Clay and blast-furnace gas cleaning sludge were used as raw materials. The chemical compositions of raw materials for their use in the production of ceramic products have been studied. The calcium- and iron-containing compounds included in the composition of the gas cleaning sludge contribute to a decrease in the temperature of the formation of solid solutions and the anorthite phase. It has been established that with the addition of sludge up to 80 wt.% into the composition of the ceramic mixture increases the likelihood of an anorthite phase formation. The physico-mechanical parameters of the obtained ceramic samples have been studied. It has been established that the amount of gas cleaning sludge in the composition of the charge is 10 – 40 wt.% allows to obtain products with compressive strength 18 % higher than the control sample. The improvement in physical and mechanical properties is associated with an increase in the amount of the formed anorthite phase, which is confirmed by the data of X-ray phase analysis.
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