溶剂法制备可降解防污涂料的工艺研究

Xinchen Yu, M. Kou, Jin Wang
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摘要

海洋防污涂料作为防止海洋污染生物附着在各种海洋设施表面的有效方法之一,得到了广泛的应用。主要类型有自抛光防污涂料和低表面能防污涂料以及仿生防污涂料。由于环保意识的增强,对环境有害的防污涂料已逐渐被取缔,因此研发新型防污涂料已成为主要的发展方向。本文以聚己内酯和聚乳酸为树脂基料,辣椒素为生物友好型防污剂,淀粉为多糖添加剂,通过调整这些材料的配比制备实验样品。采用磁力搅拌器等实验设备模拟海上挂板法,进行了添加淀粉和未添加淀粉的实验,观察并记录了淀粉对以聚己内酯、聚乳酸(PLA)等可生物降解材料为树脂基质的单组分或共混物的防污涂料的水解效果。结果表明,淀粉能促进PCL等树脂基材料的水解,获得PCL和PLA在氯仿中的溶解度,获得了一种海洋静电培养设备防污涂料的制备方法。
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Process Study on the Preparation of Degradable Antifouling Paint Coatings by Solvent Method
Marine anti-fouling coatings have been widely used as one of the effective methods to prevent marine fouling organisms from adhering to the surfaces of various marine facilities. The main types are self-polishing anti-fouling coatings and low surface energy anti-fouling coatings, and biomimetic antifouling paint. Due to the increasing awareness of environmental protection, the anti-fouling coatings harmful to the environment have been gradually banned, so the research and development of new anti-fouling coatings has become the primary direction of development.In this paper, polycaprolactone and PLA were used as resin base materials, capsaicin as bio-friendly anti-fouling agent, starch as polysaccharide additive, the experimental samples were prepared by adjusting the mixture ratio of these materials. The experiment of adding starch and unadded starch was carried out by using Magnetic stirrer and other experimental equipment to simulate the hanging board method on the sea and observed and recorded, the effect of Starch on the hydrolysis of anti-fouling coatings using single component or blends of biodegradable materials such as polycaprolactone, polylactic acid (PLA) as resin matrix was investigated.The results showed that starch could promote the hydrolysis of resin-based materials such as PCL, and the solubility of PCL and PLA in chloroform was obtained, a preparation method of antifouling coating for marine static culture equipment was obtained.
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