氧化绝缘油的太赫兹透射光谱

Nobuaki Nishimura, R. Ogura, S. Matsumoto, M. Mizuno, K. Fukunaga
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引用次数: 2

摘要

随着电力设备老化数量的增加,弄清变质绝缘油的特性具有重要意义。本文介绍了用太赫兹光谱法对氧化绝缘油透射光谱的基本研究。首先,测量了矿物绝缘油和混合绝缘油在氧气中加热后的光谱变化。其次,采用不同组成的十二烷和辛醇对绝缘油的氧化过程进行了模拟。羟基(-OH)在6 ~ 7太赫兹之间的吸收显著。氢氧根的振动变化可以观察到氢键的形成。在电力设备用的加速老化绝缘油中也发现了吸收带。
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Transmittance spectra of oxidized insulation oil using terahertz spectroscopy
The number of aged power equipment increases and it is important to clarify the characteristics of deteriorated insulating oil. This paper describes the basic study on transmittance spectra of oxidized insulating oils by terahertz spectroscopy. First, the mineral and mixture insulating oils heated in oxygen were measured and observed spectra change. Second, the oxidation process of insulating oil was modeled by using various compositions of dodecane and 2-octanol. The absorption related to hydroxyl groups (-OH) was significantly observed between 6 and 7 THz. And hydrogen bonds were observed from vibration change of OH. The absorption band was also observed in accelerated aging insulating oils used in power equipments as insulating oil.
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