使用微波(mw)功率的气体等离子体的产生和建模

M. Moisan, H. Nowakowska
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引用次数: 0

摘要

与射频产生的等离子体相比,在微波等离子体的情况下,电磁(EM)场的能量仅与电子通信,因为离子比电子重几千倍,不能响应微波(典型频率范围100 MHz-300 GHz)的e场方向的周期性变化,因此不能在电磁场中获得能量。电子的能量基本上是通过在电子场期间(足够高的气体压力)的无数次碰撞或通过电子回旋共振(低于mTorr的压力)以这种方式传递给重粒子。这导致引入了每个电子吸收功率qA和每个电子基础上的功率损失qL的概念[1]。在稳态条件下,当等离子体体积(等离子体粒子重组的体积,因此功率损失)等于从MW场吸收功率的体积时,我们得到功率平衡qA = qL,这可以显示出比通常的全局功率平衡更有信息量。定义qA,其中n为动量传递的电子碰撞频率,w为波角频率,e/me为电子荷质比,EM - e场的均方值。qA(吸收功率)的值可以调整,以精确补偿qL(功率损耗),因此qL是主要的功率参数;因此,维持放电的维持电场强度作为一个内部参数出来,即,它与操作人员无关,与一般认为的任何类型的电场持续放电相反。其他相关特征是:i)无论何时可以实现这一点,相对于消耗的体积而言,吸收功率的体积越小,维持e场的强度就越高:这导致吸收区域内部比外部更高的原子(分子)激发率(例如微放电的情况);ii)就理解射频和毫瓦放电特性而言,一个有趣的事实是,从射频域到毫瓦域,qL值随着频率的增加而降低;iii)相似定律,最初导出的直流放电,推广到包括射频和微波放电。例如,qA/p作为pR (p为气体压力,R为放电管内半径)的函数,由于qA比E2更容易测量,并且避免将后者作为外部参数考虑,因此可以很好地取代广泛使用的E/p与pR相似定律;iv)利用每电子天平的功率,可以证明电子回旋共振(ECR)条件下的电磁场强度经过最小值,而不是最大值,这与通常的说法相反;v)脉冲状态下的电场强度在足够短的脉冲长度和足够长的间隔时间下可以达到最大。
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GENERATION AND MODELING OF GASEOUS PLASMAS USING MICROWAVE (MW) POWER
In contrast to RF produced plasmas, in the case of microwave plasmas the energy from the electromagnetic (EM) field is communicated only to electrons since ions, being a few thousand times much heavier than electrons, cannot respond to the periodic changes in the direction of the E-field of microwaves (typical frequency range 100 MHz-300 GHz) and therefore cannot gain energy in the EM field. The energy of electrons is essentially transferred to heavy particles either through numerous enough collisions during the E-field period (high enough gas pressures) or through electron-cyclotron resonance (pressures below mTorr) sustaining in this way the gas discharge. This had led to introduce the concept of power absorbed per electron qA and power loss on a per electron basis qL [1]. Under steady-state conditions and when the plasma volume (the volume in which plasma particles recombine and, thus, power is lost) is equal to the volume in which power is absorbed from the MW field, we have the power balance qA = qL, which can be shown to be much informative than the usual global power balance. qA is defined as  where n is the electron collision frequency for momentum transfer, w, the wave angular frequency, e/me, the electron charge to mass ratio, and , the mean squared value of the EM E-field. The value of qA (absorbed power) is shown to adjust so as to compensate exactly for qL (power losses), which is thus the dominant power parameter; as a result, the intensity of the maintenance E-field sustaining the discharge comes out as an internal parameter, i.e., it is operator-independent, in contrast to what is generally believed whatever the kind of E-field sustained discharges. Other related features are: i) whenever this can be achieved, the smaller the volume in which power is absorbed with respect to the volume in which it is spent, the higher the intensity of the maintenance E-field: this leads to higher atomic (molecular) excitation rates inside than outside the absorption region (such is the case in micro-discharges); ii) an interesting fact as far as understanding RF and MW discharge properties is concerned is that the value of qL decreases with increasing frequency from the RF domain to that of MWs; iii) similarity laws, initially derived with DC discharges, are generalized to include RF and microwave discharges. For example, qA/p as a function of pR (p is gas pressure and R discharge-tube inner radius) replaces advantageously the widely used E/p vs. pR similarity law since qA is more easily measured than E2 and further it avoids considering the latter as an external parameter, etc.; iv) using the power per electron balance, it can be proved that the EM E-field intensity under electron cyclotron resonance (ECR) condition passes through a minimum, not a maximum, contrary to what is generally claimed; v) the E-field intensity under pulsed regime can be maximized under short enough pulse length and long enough off-time in between.
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