Zhihua Yong, Tao Liu, Xingyu Gao, Lei Yan, C. Ong, A. Wee
{"title":"Ar+溅射对钴掺杂氧化锌中钴价态和化学环境的影响","authors":"Zhihua Yong, Tao Liu, Xingyu Gao, Lei Yan, C. Ong, A. Wee","doi":"10.1142/S1793617908000136","DOIUrl":null,"url":null,"abstract":"Zn1-xCoxAl0.01O (x = 0, 0.15, 0.2, 0.3) films were fabricated on Si(100) substrates by pulsed laser deposition (PLD). X-ray diffraction (XRD) studies showed that the Co-doped ZnO films are polycrystalline with c-axis orientated wurtzite structure. Photoemission revealed a valence state of 2+ and a tetrahedral coordination of Co in the Co-doped ZnO. Ar+ sputtering was performed to investigate the changes to the valence state and the chemical environment of Co at surface and bulk. After Ar+ sputtering, the film composition was found to be closer to the starting target material. This was confirmed by the results of X-ray fluorescence (XRF) measurements, indicating the Co-doped ZnO film surface is cobalt-rich.","PeriodicalId":166807,"journal":{"name":"Advances in Synchrotron Radiation","volume":"3 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2008-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"EFFECTS OF Ar+ SPUTTERING ON VALENCE STATE AND CHEMICAL ENVIRONMENT OF COBALT IN COBALT-DOPED ZINC OXIDE\",\"authors\":\"Zhihua Yong, Tao Liu, Xingyu Gao, Lei Yan, C. Ong, A. Wee\",\"doi\":\"10.1142/S1793617908000136\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Zn1-xCoxAl0.01O (x = 0, 0.15, 0.2, 0.3) films were fabricated on Si(100) substrates by pulsed laser deposition (PLD). X-ray diffraction (XRD) studies showed that the Co-doped ZnO films are polycrystalline with c-axis orientated wurtzite structure. Photoemission revealed a valence state of 2+ and a tetrahedral coordination of Co in the Co-doped ZnO. Ar+ sputtering was performed to investigate the changes to the valence state and the chemical environment of Co at surface and bulk. After Ar+ sputtering, the film composition was found to be closer to the starting target material. This was confirmed by the results of X-ray fluorescence (XRF) measurements, indicating the Co-doped ZnO film surface is cobalt-rich.\",\"PeriodicalId\":166807,\"journal\":{\"name\":\"Advances in Synchrotron Radiation\",\"volume\":\"3 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Synchrotron Radiation\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1142/S1793617908000136\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Synchrotron Radiation","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1142/S1793617908000136","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
EFFECTS OF Ar+ SPUTTERING ON VALENCE STATE AND CHEMICAL ENVIRONMENT OF COBALT IN COBALT-DOPED ZINC OXIDE
Zn1-xCoxAl0.01O (x = 0, 0.15, 0.2, 0.3) films were fabricated on Si(100) substrates by pulsed laser deposition (PLD). X-ray diffraction (XRD) studies showed that the Co-doped ZnO films are polycrystalline with c-axis orientated wurtzite structure. Photoemission revealed a valence state of 2+ and a tetrahedral coordination of Co in the Co-doped ZnO. Ar+ sputtering was performed to investigate the changes to the valence state and the chemical environment of Co at surface and bulk. After Ar+ sputtering, the film composition was found to be closer to the starting target material. This was confirmed by the results of X-ray fluorescence (XRF) measurements, indicating the Co-doped ZnO film surface is cobalt-rich.
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