加拿大安大略省Wilberforce地区Dwyer矿萤石矿化:萤石-钙碳酸盐的显微结构指示

R. Martin, D. Schumann
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引用次数: 2

摘要

在安大略省威尔伯福斯附近的德怀尔萤石矿,矿石由方解石-萤石岩脉组成,显示出明显的流动迹象。这些岩脉和以花岗岩-二长岩岩体为代价而形成的大范围灰岩,只能用碳酸盐岩下伏体的存在来解释。岩脉由方解石和萤石带状组成,并含有与带状排列的氟磷灰石亚面体晶体。岩脉还携带有铝辉石、钛矿和bastnäsite-(Ce)晶体。氟磷灰石和艾格辉石都含有微米级的边界层熔体球,这些球在原位结晶为方解石、萤石、石英、bastnäsite-(Ce)、赤铁矿和钛矿。富ree矿物的碎片在估计至少为725°C的温度下显示出早期流变的迹象。大规模的碱交代作用发生在格伦维尔造山旋回末期,在地壳松弛时期,大约在花岗岩-二长花岗岩岩体就位2亿年之后。与其他地方的情况类似,很可能是碳酸盐岩熔体与霞石正长母熔体不混溶分离。氟-钙碳酸盐岩浆作用可能与该地区的U和Th矿化有关,并导致了bancroft - halliburton地区不同寻常的地质复杂性。
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Fluorite Mineralization at the Dwyer Mine, Wilberforce Area, Ontario, Canada: Microtextural Indications of a Fluor-Calciocarbonatite
The ore at the Dwyer fluorite mine, near Wilberforce, Ontario, consists of calcite–fluorite dikes that show clear signs of flowage. Those dikes and the large-scale development of fenites at the expense of a granite–monzonite pluton can only be explained by the existence of a subjacent body of carbonatite. The dikes consist of ribbons of calcite and fluorite and contain subhedral crystals of fluorapatite aligned with the ribbons. The dikes also carry crystals of aegirine-augite, titanite, and bastnäsite-(Ce). Both the fluorapatite and aegirine-augite contain micrometric globules of boundary-layer melt that crystallized in situ to calcite, fluorite, quartz, bastnäsite-(Ce), hematite, and titanite. Fragments of the REE-enriched fenite show signs of incipient rheomorphism at a temperature estimated to be at least 725 °C. The large-scale alkali metasomatism occurred toward the end of the Grenville orogenic cycle, at a time of crustal relaxation, roughly 200 million years after emplacement of a granite–monzonite pluton. By analogy with occurrences elsewhere, it is likely that the carbonatitic melt separated immiscibly from a nepheline syenitic parental melt. Fluor-calciocarbonatitic magmatism likely is genetically linked to the U and Th mineralization in the area and contributed to the unusual geological complexity of the Bancroft–Haliburton region.
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