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引用次数: 0

摘要

本文考虑了用比较计算的方法量化碱式碳酸镍水合物形成的标准吉布斯能的可能性。得到的经验方程可用于计算形式为xMeCO×yMe(OH)和晶体水合物- xMeCO×yMe(OH)∙zHO的无水碱式碳酸镍形成的标准吉布斯能值。
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CALCULATION OF THE STANDARD GIBBS ENERGY OF THE FORMATION OF BASIC NICKEL CARBONATES
The paper considers the possibility of quantifying the standard Gibbs energy of the formation of hydrates of basic nickel carbonates by the method of comparative calculation. Empirical equations are obtained that allow calculating the values of the standard Gibbs energy of the formation of anhydrous basic nickel carbonates of the form xMeCO×yMe(OH) and crystallohydrates - xMeCO×yMe(OH)∙zHO.
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