E. Taer, Juwita Ade Putri, N. Yanti, Apriwandi Apriwandi, R. Taslim
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引用次数: 0
摘要
红姜叶废(Zingiber Officinale Var Rubrum)被成功地加工成超级电容器电极的活性炭基材料。碳电极的制作过程从原始材料的制备、干燥、精炼、化学活化、一体化热解和中和开始。本研究的重点是化学活化剂ZnCl2,它与不同浓度的(0.1和0.5)m一起使用。活性炭粉末使用压力机印刷,以产生均匀大小的固体硬币形式的碳。样品中碳元素的优化是通过高温热解过程进行的,采用一步一体化技术。其中,在N2气体环境下从室温30℃至600℃进行碳化,然后在CO2气体环境下进行物理活化,直至高温达到800℃。表征从红姜叶活性炭样品开始,通过测量碳硬币的质量,直径和厚度来确定在热解过程中发生的收缩量。在对称双电极体系中,采用循环伏安法(CV)和恒流充放电法(GCD)对其电化学性能进行了测试。在0-1 V的低电位窗口下,在1M KOH和1M Na2SO4水溶液的影响下进行了电化学表征。当ZnCl2激活剂浓度为0.5M时,红姜叶活性炭样品的电化学性能最佳。KOH的比电容值为115.9 F/g。0.1M ZnCl2活化剂中电解液Na2SO4含量为72 F/g。通过这些结果,红姜叶作为活性炭电极的基础材料具有很大的潜力,可以提高超级电容器的性能。
POTENSI DAUN JAHE MERAH SEBAGAI BAHAN DASAR PEMBUATAN ELEKTRODA SUPERKAPASITOR
Red ginger leaf waste (Zingiber Officinale Var Rubrum) has been successfully processed as an active carbon base material for supercapacitor electrodes. The process of making carbon electrodes starts from the preparation of the original material, drying, refining, chemical activation, integrated pyrolysis and neutralization. The focus of this research is on the chemical activator ZnCl2 which is used with different concentrations of (0.1 and 0.5) M. Activated carbon powder is printed using a press to produce carbon in the form of solid coins of uniform size. The optimization of the carbon element in the sample is carried out through a pyrolysis process at high temperature with a one-stage integrated technique. Where, carbonization in the N2 gas environment is carried out starting from room temperature 30°C up to 600°C followed by physical activation until the high temperature reaches 800°C in CO2 gas environment. Characterization of activated carbon samples from red ginger leaves begins with determining the amount of shrinkage that occurs in the pyrolysis process by measuring the mass, diameter and thickness of the carbon coins. Furthermore, the electrochemical properties were tested using two methods, namely cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) in a symmetrical two-electrode system. The electrochemical characterization was carried out under the influence of an aqueous electrolyte of 1M KOH and 1M Na2SO4 at a low potential window of 0-1 V. The optimum conditions of electrochemical properties were found in the red ginger leaf activated carbon sample with a ZnCl2 activator concentration of 0.5M for the electrolyte. KOH with a specific capacitance value of 115.9 F/g. while for electrolyte Na2SO4 found in ZnCl2 activator 0.1M with a value of 72 F/g. Through these results, red ginger leaves are known to have great potential as a base material for activated carbon electrodes to improve the performance of supercapacitors.