渣浴煤气化反应的数值模拟与优化

IEEA '18 Pub Date : 2018-03-28 DOI:10.1145/3208854.3208863
Yaquan Zhan, Wenjun Duan, Q. Yu, Tianwei Wu
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引用次数: 1

摘要

高炉炉渣是钢铁工业中巨大的废能源,高炉炉渣废热的回收利用近年来受到越来越多的关注。建立了以熔融BFS为热载体的煤气化富氢合成气新工艺,在此基础上,利用ANSYS FLUENT软件采用有限速率/涡动耗散模型对气化炉内的煤气化反应进行了数值模拟,分析了熔池内气体组分的分布,研究了动力煤比(S/C)对合成气组分的影响。同时,采用基于正交试验的矩阵分析法对煤气化反应工艺进行了优化。结果表明:熔池中主要气体成分为蒸汽、H2、CO和CO2。熔池中的蒸汽和CO主要分布在气泡外,而H2和CO2主要分布在气泡中心。同时,高S/C比会降低合成气中CO的含量,不利于煤的气化过程。优化后熔池气含率提高到9.429%,BFS熔液湍流动能提高到12.88 × 10-3m2/s2, BFS熔液溅射率下降到2.024。熔融BFS的流动和熔池中气液相的混合程度增强,出口合成气的有效成分和热值也有所提高。
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Numerical Simulation and Optimization of Slag Bath Coal Gasification Reaction
Molten blast furnace slag(BFS) is a huge waste energy in iron and steel industry, the waste heat recovery of the molten BFS has attracted more and more attentions in recent years. A new process for generating hydrogen-enriched syngas by the coal gasification using molten BFS as heat carrier is built, based on this, numerical simulation of coal gasification reaction in the gasifier is carried out with finite rate/eddy dissipation model using ANSYS FLUENT, the distribution of gas components in the molten pool is analyzed and the effect of steam coal ratio(S/C) on the composition of syngas is investigated. At the same time, the coal gasification reaction process is optimized by using matrix analysis method based on orthogonal experiment. Results show that the main gas components in the molten pool are steam, H2, CO and CO2. The steam and CO in the molten pool are mainly distributed outside of the bubble, while H2 and CO2 are mainly distributed in the center of the bubble. Meanwhile, the high S/C ratio will reduce the content of CO in the syngas, which is not conducive to the process of coal gasification. After optimization, the gas holdup in the molten pool increases to 9.429%, the turbulent kinetic energy of molten BFS rises to 12.88x10-3m2/s2, and the splashing rate of molten BFS drops to 2.024. The flow of molten BFS and the mixing degree of gas-liquid phase in the molten pool are enhanced, and the effective composition and calorific value of outlet syngas are also improved.
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