{"title":"通过聚酰亚胺LB薄膜的弹性和非弹性隧道","authors":"M. Iwamoto, T. Kubota","doi":"10.1109/ICPADM.1994.413972","DOIUrl":null,"url":null,"abstract":"The electron transport mechanism through polyimide (PI) Langmuir-Blodgett (LB) films, with monolayer thickness of 0.4 nm, was investigated by means of current-voltage (I-V) measurement and Inelastic Electron Tunneling Spectroscopy (IETS). Tunnel junctions with a structure of Au/PI/Pb were examined. It was found that electrons tunnel across the PI LB films without loss of their own energy. Tunnel junctions with a PORPI monolayer sandwiched between PI layers were also examined. Here PORPI is polyimide containing tetraphenylporphyrin moiety. It was found that electrons tunnel across the junctions, accompanying the energy loss due to the excitation of vibrational modes of PORPI molecules and the excitation of electron transitions in PORPI molecules.<<ETX>>","PeriodicalId":331058,"journal":{"name":"Proceedings of 1994 4th International Conference on Properties and Applications of Dielectric Materials (ICPADM)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1994-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Elastic and inelastic tunneling through polyimide LB films\",\"authors\":\"M. Iwamoto, T. Kubota\",\"doi\":\"10.1109/ICPADM.1994.413972\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The electron transport mechanism through polyimide (PI) Langmuir-Blodgett (LB) films, with monolayer thickness of 0.4 nm, was investigated by means of current-voltage (I-V) measurement and Inelastic Electron Tunneling Spectroscopy (IETS). Tunnel junctions with a structure of Au/PI/Pb were examined. It was found that electrons tunnel across the PI LB films without loss of their own energy. Tunnel junctions with a PORPI monolayer sandwiched between PI layers were also examined. Here PORPI is polyimide containing tetraphenylporphyrin moiety. It was found that electrons tunnel across the junctions, accompanying the energy loss due to the excitation of vibrational modes of PORPI molecules and the excitation of electron transitions in PORPI molecules.<<ETX>>\",\"PeriodicalId\":331058,\"journal\":{\"name\":\"Proceedings of 1994 4th International Conference on Properties and Applications of Dielectric Materials (ICPADM)\",\"volume\":\"1 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of 1994 4th International Conference on Properties and Applications of Dielectric Materials (ICPADM)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ICPADM.1994.413972\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of 1994 4th International Conference on Properties and Applications of Dielectric Materials (ICPADM)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICPADM.1994.413972","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Elastic and inelastic tunneling through polyimide LB films
The electron transport mechanism through polyimide (PI) Langmuir-Blodgett (LB) films, with monolayer thickness of 0.4 nm, was investigated by means of current-voltage (I-V) measurement and Inelastic Electron Tunneling Spectroscopy (IETS). Tunnel junctions with a structure of Au/PI/Pb were examined. It was found that electrons tunnel across the PI LB films without loss of their own energy. Tunnel junctions with a PORPI monolayer sandwiched between PI layers were also examined. Here PORPI is polyimide containing tetraphenylporphyrin moiety. It was found that electrons tunnel across the junctions, accompanying the energy loss due to the excitation of vibrational modes of PORPI molecules and the excitation of electron transitions in PORPI molecules.<>
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