矿物学和阳离子交换容量对电阻率值的影响

Mohammad Izzat Shaffiq Azmi, Ahmad Khairul Abd Malik, A. Madun, F. Pakir, Badee Alshameri
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摘要

电阻率层析成像(ERT)是一种基于电阻率值(ERV)进行土壤地下剖面的方法,用于表征土壤厚度、裂缝带、土壤饱和度、盐度和地下水。影响电阻率值的因素有很多,如孔隙度、饱和度、矿物学、密度、阳离子交换容量(CEC)和水电阻率等。本研究通过控制矿物学因素、饱和度、孔隙度和水电阻率,研究CEC对电阻率值的影响。因此,通过了解CEC因子能够将土壤的电阻率和矿物学联系起来。本研究使用了土壤和岩石中常见的几种矿物,如高岭石、蒙脱石、伊利石、石英、云母和长石。所有被测矿物的粒度均通过0.063mm筛。对矿石的粒度分布、比重、阿特伯格极限等基本指标进行了测试。利用terameter LS2和电阻率箱测量矿石的电阻率值。采用原子吸收光谱法(AAS)对矿物经醋酸铵溶液稀释后的CEC进行了分析。与馏水混合的矿物孔隙度和饱和度控制在0.5 ~ 0.6和20% ~ 100%之间。每种矿物的CEC值不同,其中高岭石和蒙脱石的CEC值最低,最高,分别为1和70。电阻率随CEC值和饱和度的增大而减小。CEC越高的矿物,其电阻率值越低。同时,通过增加矿物的饱和度,降低其电阻率值。
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The Influence of Mineralogy and Cation Exchange Capacity toward Electrical Resistivity Value
Electrical Resistivity Tomography (ERT) is a method used for subsurface profiling in soil to characterize soil thickness, fracture zones, soil saturation, salinity and groundwater based on the electrical resistivity value (ERV). There are multiple factors that influence the electrical resistivity value, such as the porosity, degree of saturation, mineralogy, density, cation exchange capacity (CEC), and water resistivity. For this study, the effect of CEC towards resistivity value is studied via controlling the mineralogy factor, saturation, porosity and water resistivity. Thus, via understanding the CEC factor able to relate the resistivity and mineralogy of soil. This study is using a few common minerals in soil and rock, such as kaolinite, montmorillonite, illite, quartz, mica, and feldspar. The particle sizes of all tested minerals were passing 0.063mm sieve. The basic index properties of minerals such as particle size distribution, specific gravity, and Atterberg limit were tested. The instruments of Terrameter LS2 and resistivity box were used to determine the resistivity value of minerals. The Atomic Absorption Spectroscopy (AAS) machine was used to analyze the CEC of minerals via dilute with the ammonium acetate solution. The porosity and degree of saturation of minerals mixed with distill water were controlled between the range of 0.5 to 0.6 and 20% to 100%. The CEC of each mineral has different value, where the lowest and the highest minerals CEC in this study were Kaolinite and Montmorillonite at 1 and 70, respectively. The electrical resistivity values decrease with the increasing of CEC value and degree of saturation. The mineral that has higher CEC indicates lower resistivity value. Meanwhile, via increasing the degree of saturation of minerals were decrease its resistivity values.
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