掺杂氧化铜纳米颗粒的pvdf基电解质聚合物锂电池:制造技术与性能

E. Podlesnov, M.G. Nigamatdianov, A.O. Safronova, M. Dorogov
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引用次数: 0

摘要

综述了聚合物锂电池电解质材料的研究现状,并对金属氧化物纳米颗粒在聚合物锂电池电解质中的应用前景进行了展望。本文还介绍了以聚偏氟乙烯为基料,掺杂氧化铜纳米颗粒制备凝胶聚合物电解质的方法,并用电化学阻抗谱法测定了离子电导率。用合成的电解质和LiFePO4电极组装电池并在不同电流下循环。在电解液中掺入氧化铜纳米颗粒(重量0.1%),电池循环稳定,容量高。
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Lithium Polymer Battery with PVDF-based Electrolyte Doped with Copper Oxide Nanoparticles: Manufacturing Technology and Properties
An overview of electrolyte materials for lithium polymer batteries and the prospects for adding metal oxide nanoparticles to the electrolyte are presented in this paper. A procedure for the synthesis of a gel polymer electrolyte based on polyvinylidene fluoride doped with copper oxide nanoparticles is also described, and the ionic conductivity is measured by the electrochemical impedance spectroscopy. Cells with the synthesized electrolyte and LiFePO4 electrode have been assembled and cycled at different currents. Stable cycling and high capacity have been exhibited by the cell with electrolyte doped with copper oxide nanoparticle (wt. 0.1%).
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