Shale Characterization Using T1-T2* Magnetic Resonance Relaxation Correlation Measurement at Low and High Magnetic Fields

Shale characterization is complicated by low porosity and low permeability. Nano-porosity and a high degree of heterogeneity present further difficulties. 1H magnetic resonance (MR) methods have great potential to provide quantitative and spatially resolved information on fluids present in porous rocks. The shale MR response, however, is challenging to interpret due to short-lived signals that complicate quantitative signal detection and imaging. Multicomponent signals require high-resolution methods for adequate signal differentiation. MR methods must cope with low measurement sensitivity at low field. In this paper, T1-T2* and Look-Locker T1*-T2* methods were employed to resolve the shale signal for water, oil, and kerogen at high and low field. This permits fluid quantification and kerogen assessment. The T1-T2* measurement was employed to understand and control contrast in the single-point ramped imaging with T1 enhancement (SPRITE) imaging method. This permitted imaging that gave separate images of water and oil. Water absorption/desorption, evaporation, step pyrolysis, and water uptake experiments were monitored using T1-T2* measurement and MR imaging. The results showed (i) the capability of the T1-T2* measurement to differentiate and quantify kerogen, oil, and water in shales, (ii) the characterization of shale heterogeneity on the core plug scale, and (iii) demonstrated the key role of wettability in determining the spatial distribution of water in shales.