不锈钢网催化废镁基材料在氯化铁溶液中水解产氢的评价

V. Hashe, T. Jen
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摘要

氢经济越来越受到世界各国的重视,并将很快成为世界各国的优先发展方向。氢气具有广泛的优点,其中最大的优点是它作为绿色能源载体的能力和灵活性。越来越多的汽车制造商正在效仿,从燃料电池电动汽车的原型设计转向商业演示。目前,天然气和煤炭是最便宜的氢气来源,而且很可能继续如此。本研究以报废产品中的镁废料为原料,在氯化铁水溶液的存在下生成氢气。镁(Mg)与水反应缓慢,在室温下释放氢,随后在其表面形成氢氧化镁。加入1.5 wt%的氯化铁加速了这个反应。结果表明,氯化铁是一种优良的水解促进剂,不锈钢是一种有效的催化剂。反应平均在3600秒内产生2700mL氢气。
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Evaluation of Hydrogen Yield by Hydrolysis from Waste Magnesium Based Materials Catalysed By Stainless Steel Net in Iron Chloride Solution
Hydrogen (H2) economy more and more attention and it is soon to become a priority development to all nations around the globe. H2 offers a wide range of benefits and the greatest of them all is its ability and flexibility to be used as a green energy carrier. More and more car manufacturers are following suit in moving from prototyping to commercial demonstrations of fuel cell electric cars. Natural gas and coal are currently the cheapest sources of hydrogen and are likely to remain so. In the present study, magnesium waste-based materials from end of life products were used as raw materials in the presence of iron chloride added water solution to generate hydrogen gas. Magnesium (Mg) reacts slowly with water and releases hydrogen at room temperature and this is followed by the formation of magnesium hydroxide on its surface. This reaction was accelerated by an addition of 1.5 wt% of iron chloride. The results confirmed iron chloride as an excellent hydrolysis reaction accelerator with stainless steel as an effective catalyst. On average, the reaction yielded 2700mL of H2 over 3600 seconds.
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