甘油氧化制丙烯酸复合金属氧化物催化剂的研究进展

三三 于, 自轩 卢, 双明 李
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引用次数: 0

摘要

随着化石燃料的短缺及其利用所带来的环境问题,可再生生物质资源逐渐成为燃料和化学品生产的重要来源。近年来,甘油作为生物柴油生产的主要副产物受到了广泛的关注。利用甘油生产高附加值产品及相关转化技术的开发也成为国内外学者关注的热点。与纳米、纳米、纳米转化技术相比,甘油选择性氧化制丙烯酸已显示出广阔的发展前景。对该反应特别是催化剂的研究具有重要的经济和社会意义。综述了甘油选择性氧化制丙烯酸的复合金属氧化物催化剂的研究现状。简要介绍了反应中使用的催化体系的种类以及对甘油氧化制丙烯酸的催化反应机理的认识。并对存在的问题和未来的发展前景进行了分析和展望。
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Research Progress of Composite Metal Oxide Catalysts for the Oxidation of Glycerol to Acrylic Acid
: With the shortage of fossil fuels and the environmental problems caused by their utilization, renewable biomass resources have gradually become an important source for the production of fuel and chemicals. In recent years, as the main by-product of biodiesel production, glycerol has attracted widespread attention. The utilization of glycerol to produce high value-added products and the development of relevant conversion technologies have also be­ come a hot spot for scholars at h o m e and abroad. A m o n g m a n y conversion technologies, the selective oxidation of glycerin to acrylic acid has shown broad development prospects. It has important economic and social significance to study the reaction and especially the catalyst. This article summarizes the current research status of composite metal oxide catalysts for the selective oxidation of glycerol to aciylic acid. The cuiTent types of catalytic systems used in the reaction and the understanding of the catalytic reaction mechanism of glycerol oxidation to aciylic acid are brief­ ly introduced. Moreover, the existing problems and future prospects are also analyzed and expected.
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