Al2O3悬浮液的粒子间电势

C. A. Gutiérrez, R. Moreno
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引用次数: 12

摘要

摘要通过评估分散剂浓度对43体积-% Al2O3水溶液悬浮液流变性能的影响,研究了其最佳分散条件。采用一种商用聚电解质作为分散剂。考虑静电和空间作用,计算了粒子对电势。位阻势的变化会使势能曲线的形状和水平发生显著变化,从而可以根据DLVO方程预测应凝固的悬浮液的稳定性。胶体稳定性和流变行为与滑移铸造Al2O3坯体的生坯密度和烧结密度有关。
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Interparticle potentials of aqueous Al2O3 suspensions
Abstract Optimum dispersing conditions for 43 vol.-% aqueous Al2O3 suspensions have been studied by assessing rheological behaviour as a function of dispersant concentration. A commercial polyelectrolyte was used as dispersant. The particle pair potentials have been calculated by considering the electrostatic and steric contributions. Variations in the steric potential produce significant changes in the shape and level of the potential energy curves and allow the prediction of the stability of suspensions that should coagulate according to the DLVO equation. Colloidal stability and rheological behaviour are correlated with the green and sintered densities of Al2O3 bodies produced by slip casting.
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