锂离子硬币半电池制造的稳健方法

M. S. Arsha, Jawad Arif, Zubair Rehman
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摘要

锂离子电池已经在消费电子产品、国防部门、光伏(PV)系统和电动汽车(EV)中得到了应用,因为与同类产品相比,锂离子电池具有高电荷密度、寿命周期、长电池寿命和低放电等巨大优势。由于电动汽车的蓬勃发展和对储能选择的需求不断增加,人们正在进行大量研究,以增加锂离子电池的容量,同时减小尺寸和充电速率。为此,电极材料的组成、比例和电解质对于获得最佳的锂离子电池能量密度起着至关重要的作用。在本研究中,提出了半电池(硬币)制造方法,供学术研究人员和工业研发人员选择材料。该研究为研究人员提供了完整的锂离子硬币电池制造方法,使他们能够制造高质量的半硬币电池,并具有良好的半电池重现性。研究还介绍了电化学电池的化学性质以及对阳极、阴极和电解质材料选择的要求。采用上述方法制备了半电池。讨论了锂离子半电池的等效模型,并在不同的C速率下进行了恒流测量。实验证明,C率越高,电池容量越低。
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Robust Method of Lithium Ion Coin Half-Cell Fabrication
Lithium Ion batteries have found their applications in consumer electronics, the defense sector, Photovoltaic (PV) systems, and Electric Vehicles (EV) due to their immense benefits when compared to their counterparts such as high charge density, life cycles, long battery life, and low discharge. Due to the boom in EVs and increasing demand for energy storage options, a lot of research is being carried out to increase the capacity of Li-ion batteries with decreased size and charging rates. For that, electrode material composition, ratios, and electrolytes play a vital role to get the best from the Li-ion battery fabrication in terms of energy density. In this study, the half-cell (Coin) fabrication method is presented for academic researchers and industrial R&D for material selection. The study presents the complete method of fabrication of Li-ion coin cells for the researchers to enable them to fabricate their high-quality half-coin cells with good reproducibility of half cells. The study also presents the chemistry of the electrochemical cells and requirements of the material selection for Anode, cathode, and electrolyte. By following the mentioned method, Half-cell is fabricated. The equivalent model of the Li-ion half-cell is discussed along with Galvanostatic measurements at different C rates. It was verified that the higher the C rates, the lower the capacity of the cell.
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