硬质聚异氰脲酸酯泡沫(PIR)在老化条件下导热系数的变化分析

Tomas Makaveckas, R. Bliūdžius, Aurelija Levinskytė
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摘要

。对于大多数建筑保温材料,其导热系数与温度的依赖关系接近线性,并随着材料温度的升高而增大,但聚异氰脲酸酯泡沫(PIR)的导热系数在较低温度范围内增大,因此在寒冷季节采用该材料保温的隔墙传热增加。PIR的导热系数在老化过程中也会增加,特别是在后期的使用期间,这是不包括在用于确定声明导热系数值的标准老化程序中的。此外,PIR如何对特定温度和其他气候条件作出反应,以及它失去热性能的速度有多快,这些信息也缺乏。本实验研究的目的是分析热导率随老化温度的变化。制备30、50 mm厚的PIR试样,在试验开始前用热流计FOX 314测量所有试样在标准条件下的导热系数,并在一定温度下保存21 d后,在每个老化阶段再次测量试样的导热系数。结果表明:在较高温度(+50℃和+70℃)下,PIR的导热系数增加最多(可达10%),而在负温度(-18℃)下,PIR的导热系数变化影响较小。
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Analysis of the Variation of Thermal Conductivity of Rigid Polyisocyanurate Foam (PIR) in The Context of Aging
. For most building insulation materials, dependency of the thermal conductivity on temperature is close to linear, and it increases with rising materials temperature, but the thermal conductivity of the polyisocyanurate foam (PIR) increases in the lower temperature range, so the heat transfer through the partition insulated with this material is increased in the cold season. The thermal conductivity of PIR also increases during the aging process, especially during the later operating period, which is not covered by the standard aging procedure used to determine the declared thermal conductivity value. Also, there is a lack of information how PIR reacts to the certain temperatures and other climate conditions, and how fast it loses its thermal properties. The aim of this experimental research was to analyse the change of the thermal conductivity depending on aging temperature. 30, 50 mm thick PIR samples were prepared for the test, and the thermal conductivity of all specimens was measured at the standard conditions prior to the start of the test using the heat flow meter FOX 314, and again after each stage of aging, when the samples were kept at the certain temperature for 21 days. The results showed that the thermal conductivity of PIR increases more (up to 10 %) when kept at higher temperatures (+50 ° C, and +70 ° C), and after specimens undergo negative temperatures (-18 ° C) it has a minor influence to the change of thermal conductivity of PIR.
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