{"title":"亚临界水中含碳生物基材料一锅绿色催化制备3-氨基苯甲酸","authors":"Sarra Tadrent, C. Len","doi":"10.3390/eccs2020-07541","DOIUrl":null,"url":null,"abstract":": A green and sustainable approach for the production of 3-aminobenzoic acid (3-ABA) from 3-nitrobenzaldehyde promoted by NORIT GAC 12-40 as a carbonaceous bio-based material was successfully achieved in subcritical water. The process involves two successive reactions: reduction of the nitro group and oxidation of the formyl group. At 300 °C under 90 bar for 6 h, the yield of 3-ABA is 59%.","PeriodicalId":151361,"journal":{"name":"Proceedings of 1st International Electronic Conference on Catalysis Sciences","volume":"28 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2020-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-Pot Green Catalytic Preparation of 3-Aminobenzoic Acid in the Presence of Carbonaceous Bio-Based Materials in Subcritical Water\",\"authors\":\"Sarra Tadrent, C. Len\",\"doi\":\"10.3390/eccs2020-07541\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": A green and sustainable approach for the production of 3-aminobenzoic acid (3-ABA) from 3-nitrobenzaldehyde promoted by NORIT GAC 12-40 as a carbonaceous bio-based material was successfully achieved in subcritical water. The process involves two successive reactions: reduction of the nitro group and oxidation of the formyl group. At 300 °C under 90 bar for 6 h, the yield of 3-ABA is 59%.\",\"PeriodicalId\":151361,\"journal\":{\"name\":\"Proceedings of 1st International Electronic Conference on Catalysis Sciences\",\"volume\":\"28 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-11-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of 1st International Electronic Conference on Catalysis Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/eccs2020-07541\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of 1st International Electronic Conference on Catalysis Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/eccs2020-07541","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
One-Pot Green Catalytic Preparation of 3-Aminobenzoic Acid in the Presence of Carbonaceous Bio-Based Materials in Subcritical Water
: A green and sustainable approach for the production of 3-aminobenzoic acid (3-ABA) from 3-nitrobenzaldehyde promoted by NORIT GAC 12-40 as a carbonaceous bio-based material was successfully achieved in subcritical water. The process involves two successive reactions: reduction of the nitro group and oxidation of the formyl group. At 300 °C under 90 bar for 6 h, the yield of 3-ABA is 59%.