氟化胺的合成:个人叙述

IF 3.3 Q2 CHEMISTRY, MULTIDISCIPLINARY ACS Organic & Inorganic Au Pub Date : 2023-09-05 DOI:10.1021/acsorginorgau.3c00029

Yi Yang, Alexis Taponard, Julien. C. Vantourout* and Anis Tlili*,

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引用次数: 0

摘要

本报告重点介绍了我们实验室最近在开发合成氟化胺的新策略方面做出的贡献。这些策略使从业人员能够使用二氧化碳或 CS2 作为良性 C1 源，高效地获得氨基甲酰氟、硫代氨基甲酰氟以及三氟甲基胺。此外，我们还合成了一种新型 N(SCF3)CF3 分子。值得注意的是，我们证明这种试剂还可用于基于自由基或亲电的三氟甲基硫代反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis of Fluorinated Amines: A Personal Account

This Account highlights the recent contributions made by our laboratory in the development of novel strategies to synthesize fluorinated amines. These strategies allow the practitioner to efficiently access carbamoyl fluorides, thiocarbamoyl fluorides as well as trifluoromethylamines using CO₂ or CS₂ as benign C1 sources. In addition, a novel N(SCF₃)CF₃ moiety was synthesized. Noteworthy, we demonstrated that this reagent could also be used in radical- or electrophilic-based trifluoromethylthiolation reactions.

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来源期刊

ACS Organic & Inorganic Au 有机化学、无机化学-

CiteScore

4.10

自引率

0.00%

发文量

期刊介绍： ACS Organic & Inorganic Au is an open access journal that publishes original experimental and theoretical/computational studies on organic organometallic inorganic crystal growth and engineering and organic process chemistry. Short letters comprehensive articles reviews and perspectives are welcome on topics that include:Organic chemistry Organometallic chemistry Inorganic Chemistry and Organic Process Chemistry.

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