静电纺丝法制备TiO2纳米结构及其光催化吸收光谱分析

Luana Góes Soares, A. K. Alves
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摘要

静电纺丝法合成纤维可以获得具有良好柔韧性、光学和催化性能、高表面积和高孔隙率的一维材料纳米结构。它们可用于催化剂、太阳能电池、燃料电池、膜和氢电池等应用。在此我们强调,文献中很少有报道描述TiO2的光学和光催化性能之间存在的协同作用,以及这种协同作用对氧空位形成的影响,这是导致该光催化剂光催化活性提高的原因。因此,本文采用静电纺丝法合成了TiO2纳米纤维。这些纳米纤维在650°C至800°C之间进行热处理,并通过扫描电子显微镜(SEM)进行形貌表征,x射线衍射(XRD)进行晶相表征,通过125 mL 20 ppm甲基橙染料溶液样品的降解测试和比色法进行光活性表征。结果表明,经过650℃热处理的TiO2样品在染料降解和不同颜色的反射方面更有效,这可能是由于TiO2的化学和物理性质的结合,同时降解染料并表现出不同颜色之间的变化。
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Obtaining TiO2 Nanostructures by Electrospinning and Analysis of Absorbance in the UVA Spectrum for Photocatalytic Application
The synthesis of fibers by electrospinning allows for obtaining nanostructures of one-dimensional materials with good flexibility, optical and catalytic properties, high surface area and porosity. They can be used in applications such as: catalysts, solar cells, fuel cells, membranes, and hydrogen batteries, among others. Here we emphasize that few reports in the literature describe the existing synergism between the optical and photocatalytic properties of TiO2, and the influence of this synergism on the formation of oxygen vacancies, which are responsible for the increase of the photocatalytic activity of this photocatalyst. Therefore, in this work we synthesize TiO2 nanofibers by electrospinning. These nanofibers were thermally treated between 650°C and 800°C, and characterized according to: morphology by scanning electron microscopy (SEM), crystalline phases by X-ray diffraction (XRD), photoactivity through degradation tests of 125 mL of a sample of 20 ppm methyl orange dye solution and by colorimetry. The results point to the TiO2 sample heat-treated at 650°C being more effective in the dye degradation and the reflection of different colors, possibly due to the combination of the chemical and physical properties of TiO2, which at the same time degrade the dye and express variations between different colors.
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