Matthiasweilite, PbTe4+O3,一种来自美国内华达州林肯县Delamar矿的碲矿新矿物

A. R. Kampf, Owen P. Missen, S. Mills, Chiu‐Shun Ma, R. Housley, Marek Chorazewicz, J. Marty, M. Coolbaugh, Koichi Momma
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引用次数: 1

摘要

Matthiasweilite (IMA2021-069), Pb2+Te4+O3,是在美国内华达州林肯县Delamar矿发现的一种新矿物。它是一种次生矿物,与阿长石、黄铜矿、北星矿和其他富石英基质中的氧盐伴生,在蚀变原生矿石中与阿长石、四面体(锌)、天然金以及其他硫化物和硒化物一起发育。这种矿物以紧密交织的浅黄色晶体团块的形式出现。条纹为白色,光泽为精钢,莫氏硬度为2½,韧性脆,断口为贝壳状;没有明显的乳沟。经验公式计算出的密度为7.282 g/cm3。电子探针微量分析数据,假设O = 3,得到经验公式Pb0.99Te4+1.01O3。Matthiasweilite为三斜体,空间群P,胞元参数a = 7.0256(4), b = 10.6345(6), c = 11.9965(8) Å, α = 78.513(6), β = 83.104(6), γ = 84.083(6)°,V = 869.10(9) Å3, Z = 10。晶体结构(对于3416个I > 2σI反射,R1 = 0.0523)由Te4+O3三角形金字塔组成,这些金字塔通过相对较短的(<2.6 Å) Pb-O键连接形成框架。
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Matthiasweilite, PbTe4+O3, a New Tellurite Mineral from the Delamar Mine, Lincoln County, Nevada, USA
Matthiasweilite (IMA2021-069), Pb2+Te4+O3, is a new mineral discovered at the Delamar mine, Lincoln County, Nevada, USA. It is a secondary mineral, associated with adanite, choloalite, northstarite, and other oxysalts in a quartz-rich matrix, that developed in an altered primary ore along with altaite, tetrahedrite-(Zn), native gold, and other sulfides and selenides. The mineral occurs as tightly intergrown masses of light yellow crystals. The streak is white, luster is adamantine, Mohs hardness is 2½, tenacity is brittle, and fracture is conchoidal; no obvious cleavage is present. The calculated density is 7.282 g/cm3 for the empirical formula. Data from electron probe microanalysis and assuming O = 3 gives the empirical formula Pb0.99Te4+1.01O3. Matthiasweilite is triclinic, space group P, with cell parameters a = 7.0256(4), b = 10.6345(6), c = 11.9965(8) Å, α = 78.513(6), β = 83.104(6), γ = 84.083(6)°, V = 869.10(9) Å3, and Z = 10. The crystal structure (R1 = 0.0523 for 3416 I > 2σI reflections) consists of Te4+O3 trigonal pyramids that are linked via relatively short (<2.6 Å) Pb–O bonds to form a framework.
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