Retno Wulandari, Nugrahani Primary Putri
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引用次数: 3

摘要

本文报道了用不同的掺杂剂HCl、H2SO4和富马酸(FA)氧化聚合法制备可溶性聚苯胺。这种掺杂剂的变化是为了获得具有最佳溶解度和电导率的聚苯胺。FTIR表征结果表明,合成的样品中有几个特征聚苯胺键。与PANi/HCl和PANi/ h2so4相比,浓度为1M的PANi/FA在NMP溶剂中的溶解度最佳,溶解度值为5.7%。所有样品的电导率均采用两点探针法测定。PANi/ HCl浓度为1M时的电导率优于PANi/FA和PANi/ h2so4,其电导率为48 × 10 -4 S/cm。用扫描电镜观察了氧化后聚苯胺粉末的形貌。扫描电镜结果表明,聚苯胺的形态为相互连接的海绵状。
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Sintesis Soluble Polianilin dengan Variasi Jenis dan Konsentrasi Dopan
This study reports the synthesis of soluble polyaniline by the oxidation polymerization method with various dopants HCl, H2SO4, and Fumaric acid (FA). This dopant variation is carried out to obtain polyaniline with optimum solubility and electrical conductivity. The results of FTIR characterization showed several characteristic polyaniline bonds from the samples that had been synthesized. PANi/FA with a concentration of 1M has the best solubility compared to PANi/HCl and PANi/H 2 SO 4 , with a solubility value of 5.7% in NMP solvents. The electrical conductivity of all samples was measured by the two-point probe method. PANi / HCl with a concentration of 1M has the best conductivity than PANi/FA and PANi/H 2 SO 4 with a value of 48 x10 -4 S/cm. The morphology of the oxidized polyaniline powder was observed using SEM. SEM results showed the morphology of polyaniline in the form of an interconnected sponge.
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