膨润土催化裂化聚丙烯废塑料制备液体燃料

Dwi Miftha Kurnia, M. Faizal
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摘要

摘要本项目工作的目的是将废塑料转化为有用的燃料范围碳氢化合物混合物。在固定床反应器中,以膨润土为催化剂,在150 ~ 350℃的5个温度范围内,催化剂比例为4%,进行了聚丙烯塑料废弃物(矿物杯)的催化裂化工艺。所产生的液体燃料的数量以及所产生的液体燃料的成分由气相色谱-质谱法测定。考察了裂解温度、催化剂质量等参数对产物收率的影响。膨润土催化聚丙烯废塑料裂解的最佳条件是催化剂质量为4%或20 g,温度为350℃。在350℃条件下,20 g膨润土催化剂的产液率最高,为41.5%。当温度为350℃时,液态产物中C6H14、C7H16和c8h18的最高百分含量分别为16.92%、18.48%和12.22%。
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Liquid Fuel From Polypropylene Plastic Wastes with Bentonite as Catalyst by Catalytic Cracking Process
Abstract. The aim of this project work is to convert waste plastics into useful fuel range hydrocarbon mixture. The catalytic cracking process of polypropylene plastic waste (mineral water cup) was performed in a fixed-bed reactor with bentonite catalyst, at five temperatures ranging from 150 to 350oC with percent catalyst of 4%.The amounts of liquid fuel produced, as well as the compositions of the resulting liquid fuel, were determined by Gas Chromatography-Mass Spectrometry. The influences of cracking parameters, such as temperature and catalyst mass, on product yields were investigated. The optimum conditions cracking of polypropylene plastics waste with bentonite as catalyst is at temperature of 350oC with 4% catalyst mass or20 grams. The highest liquid yield (41.5%) was obtained using 20 gram Bentonite catalyst at 350oC. The highest percent composition of C6H14, C7H16 andC8H18 in liquid product  is 16.92%, 18.48%, and 12.22% respectively at temperature of 350oC.
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