溶胶-凝胶法制备Ga2O3薄膜的研究进展

X. Zhang, V. Spiridonov, D. I. Panov, I. Sosnin, A. Romanov
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摘要

目前,氧化镓(Ga2O3)作为一种宽禁带半导体材料在各个应用领域受到越来越多的关注。因此,人们在制备和研究大块Ga2O3材料、Ga2O3薄膜和Ga2O3纳米线方面做了大量的努力。对于Ga2O3薄膜,有多种制备方法,如金属-有机化学气相沉积、氢化物气相外延、脉冲激光沉积、分子束外延、频率磁控溅射、原子层沉积、湿化学、溶胶-凝胶等。本文综述了溶胶-凝胶法制备Ga2O3薄膜的研究进展。溶胶-凝胶法包括浸涂法、旋涂法、喷雾热解法和滴铸法。总结了溶胶-凝胶法制备β-Ga2O3薄膜的研究进展,并对其进行了展望。讨论了溶胶-凝胶法制备Ga2O3薄膜的多态性、结构和性能。
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Preparation of Ga2O3 Thin Films by Sol-Gel Method—a Concise Review
Nowadays, gallium oxide (Ga2O3) as a wide bandgap semiconductor material is acquiring more and more attention in various practical areas. As a result, there has been a lot of efforts to fabricate and study bulk Ga2O3 material, Ga2O3 thin films, and Ga2O3 nanowires. For Ga2O3 films, there exists a variety of preparation methods such as metal-organic chemical vapor deposition, hydride vapor phase epitaxy, pulsed laser deposition, molecular beam epitaxy, frequency magnetron sputtering, atomic layer deposition, wet chemistry, and sol-gel. This concise review focuses on the preparation of Ga2O3 thin films by sol-gel methods. Sol-gel methods include dip-coating, spin-coating, spray pyrolysis, and drop casting technique. The details on the fabrication of β-Ga2O3 thin films by sol-gel method are summarized and prospected. Polymorphism, structure and properties of sol-gel prepared Ga2O3 films are discussed.
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