Co [AM-AMPS-MALEIC-AAC]/ PEI-MBA纳米复合水凝胶在油藏防砂中的性能研究

Baghban Salehi M
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引用次数: 0

摘要

出砂是砂岩储层油气开采的主要挑战之一。生产损失、地层破坏、腐蚀和设备故障都是出砂的后果。采用各种机械和化学方法控制出砂。最有效的化学方法之一是注入水凝胶,但由于水凝胶在恶劣的储层条件下稳定性差,其应用受到限制。为了克服这些限制,开发并合成了具有优异粘弹性和双交联性能的Co [AMAMPS-MALEIC-AAC]/PEI-MBA纳米复合水凝胶。利用膨胀、流变和形态测试来预测生产的纳米复合材料在恶劣的伊朗油藏中的有效性和性能。结果表明,在环境温度(25℃,注射时)和储层温度(90℃,放置于多孔介质中)下,蒸馏水中的最大溶胀比分别为8.5和94,地层水中的最大溶胀比分别为5.4和10.8。x射线衍射测试结果表明,纳米颗粒在整个结构中均匀分布。此外,根据热强度测试的结果,样品的热稳定性高达90°C,降解小于0.6 wt%。应变扫描、频率扫描和应力应变测试的结果表明,存在一个坚固的三维粘弹性结构,应变高达100%,频率为100hz。在恒定频率为1 Hz的应变扫描试验中,最大存储模量为27,000 Pa,在恒定应变为1%的频率扫描试验中,最大存储模量为18,000 pascal。应力应变试验表明,合成材料的极限抗拉强度为4630帕斯卡。这些特性使得上述纳米复合水凝胶非常适合用于多孔介质。
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Investigating the Performance of Co [AM-AMPS-MALEIC-AAC]/ PEI-MBA Nanocomposite Hydrogel in Sand Control from Oil Reservoirs
Sand production is one of the major challenges in oil and gas production from sandstone reservoirs. Production losses, formation damage, corrosion, and equipment failure are all consequences of sand production. Various mechanical and chemical methods are used to control sand production. One of the most efficient chemical methods is the injection of hydrogels, but its application has been constrained by the hydrogels' weak stability in the harsh conditions of the reservoir. A Co [AMAMPS-MALEIC-AAC]/PEI-MBA nanocomposite hydrogel with superior viscoelastic properties and double crosslinking was developed and synthesized to overcome these restrictions. Swelling, rheology, and morphology tests were utilized to predict the produced nanocomposite's effectiveness and performance in the harsh Iranian reservoirs. According to the obtained results, at ambient temperature (25°C, during injection) and reservoir temperature (90°C, placed in a porous medium), in distilled water, the maximum swelling ratio was 8.5 and 94, and in formation water, the maximum swelling ratio was 5.4 and 10.8, respectively. The X-ray diffraction test findings show that the nanoparticles are uniformly distributed throughout the structure. Also, according to the results of the thermal strength test, the sample’s thermal stability up to 90°C was confirmed with less than 0.6 wt% degradation. The results of the strain sweep, frequency sweep and stress-strain tests demonstrate the existence of a robust, three-dimensional, and viscoelastic structure up to a strain of 100% and a frequency of 100 Hz. In the strain sweep test with a constant frequency of 1 Hz, the maximum storage modulus was reported as 27,000 Pa, and in the frequency sweep test with a constant strain of 1%, 18,000 Pascals were reported. The stress-strain test revealed that the ultimate tensile strength of the synthesized material was 4630 pascals. These characteristics make the aforementioned nanocomposite hydrogel ideal for usage in porous media.
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