低密度聚乙烯与银纳米复合材料的高场导电性

Qiaohua Wang, Y. Yin, Zhe Li, Xuguang Li, P. Jiang
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引用次数: 1

摘要

研究了纳米Ag/低密度聚乙烯(LDPE)和纯聚乙烯复合材料的高场导电性,以及纳米Ag含量对高场导电性的影响。采用Schottky效应、Poole-Frenkel效应、空间电荷限制传导(SCLC)和离子跳跃传导来拟合结果。指出空间电荷限制传导和Poole-Frenkel效应并不适用于所有样品。然而,我们发现肖特基效应很适合于纳米Ag/LDPE复合材料,并且根据经验数据计算的纳米复合材料的离子希望距离表明,离子跳跃传导适合于纳米Ag/LDPE复合材料。
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High field conduction behavior of nanocomposite of low-density polyethylene and Ag nanoparticles
High field conduction of the composite of nano Ag/low-density polyethylene (LDPE) and pure polyethylene is studied, as well as the effect of the contents of nano Ag on high field conduction. Schottky effect, Poole-Frenkel effect, space-charge-limited conduction (SCLC), and ion hopping conduction are used to fit the results. It is pointed out that both space-charge-limited conduction and Poole-Frenkel effect do not fit well for all of the samples. However, it is found that Schottky effect fits well for nano Ag/LDPE composites, and the ion hoping distance of the nanocomposite calculated from the experience data shows that ion hopping conduction fits for the composite of nano Ag/LDPE.
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