电晕放电反应器中等离子体化学反应去除一氧化氮和二氧化硫

L. Dong, S. Lan, J.X. Yang, X. Chi
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引用次数: 8

摘要

近年来,等离子体化学在气体净化中的应用日益突出,主要是从能量的角度考虑。通常,气体处理是在室温或高于室温的条件下由传统的干式电晕反应器进行的。然而,这种处理仍然不足以去除烟气混合物中存在的某些稳定气体。本文提出了一种能在低温常压下同时去除NO和SO/ sub2 /的湿式电晕反应器。实验结果表明,湿式反应器对NO和SO/sub / 2的去除率均高于干式反应器。NO主要通过与O和O/sub - 3/反应氧化为NO/sub - 2/, NO/sub - 2/通过与H/sub - 2/O生成的OH反应生成HNO/sub - 3/。大部分的SO/sub 2/去除是由于水膜的吸收,放电等离子体的增强作用很小。
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Plasma chemical reaction for nitric oxide and sulfur dioxide removal in corona discharge reactor
Application of plasma chemistry for gas cleaning is gaining prominence in recent years, mainly from the energy consideration point of view. Normally, the gas treatment is carried out at or above room temperature by the conventional dry-type corona reactor. However, this treatment is still inadequate for the removal of certain stable gases present in the flue gas mixture. In this work, a wet-type corona reactor is presented that can simultaneously remove NO and SO/sub 2/ at low temperatures and at atmospheric pressure. The experimental results show both removal rate of NO and SO/sub 2/ are improved in wet-type reactor than that of dry-type reactor. NO is mostly oxidized into NO/sub 2/ by the reaction with O and O/sub 3/ and NO/sub 2/ is change into HNO/sub 3/ by the reaction with OH, which is generated from H/sub 2/O. Most of the SO/sub 2/ removal is attributed to the absorption into the water film and the enhancement by the discharge plasma is small.
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